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The synthesis of some intermediates for use in the preparation of analogs of salicylaldehyde ethylenediimine cobalt (salcomine)

Geissman, T. A. and Schlatter, Maurice J. and Webb, Irving D. and Roberts, John D. (1946) The synthesis of some intermediates for use in the preparation of analogs of salicylaldehyde ethylenediimine cobalt (salcomine). Journal of Organic Chemistry, 11 (6). pp. 741-750. ISSN 0022-3263. http://resolver.caltech.edu/CaltechAUTHORS:20150930-135821351

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Abstract

As part of a study having for its object the examination of the oxygen-carrying properties of chelate compounds of the type exemplified by salicylaldehyde ethylenediimine cobalt (“Salcomine”) (I) a large number of substances were prepared and tested in an effort to determine the structural requirements for activity and to discover chelates with oxygen-carrying properties superior to those of I. Among the practical improvements sought were (a) greater stability than Salcomine in repeated passage through the cycle of oxygenation and deoxygenation; (b) greater oxygen capacity (over the capacity of one atom of oxygen per mole of chelate possessed by Salcomine); and (e) increased rates of oxygenation and deoxygenation under conveniently attainable temperature and pressure conditions.


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http://dx.doi.org/10.1021/jo01176a015DOIArticle
http://pubs.acs.org/doi/abs/10.1021/jo01176a015PublisherArticle
Additional Information:© 1946 American Chemical Society. The work described in this paper was carried out as part of a program of research under Division 11, Section 1, of the National Defense Research Committee, under a contract between the Office of Scientific Research and Development and the University of California.
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National Defense Research CommitteeUNSPECIFIED
Record Number:CaltechAUTHORS:20150930-135821351
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20150930-135821351
Official Citation:THE SYNTHESIS OF SOME INTERMEDIATES FOR USE IN THE PREPARATION OF ANALOGS OF SALICYLALDEHYDE ETHYLENEDIIMINE COBALT (“SALCOMINE”) T. A. GEISSMAN, MAURICE J. SCHLATTER, IRVING D. WEBB, and JOHN D. ROBERTS The Journal of Organic Chemistry 1946 11 (6), 741-750 DOI: 10.1021/jo01176a015
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:60625
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:13 Oct 2015 21:50
Last Modified:13 Feb 2019 18:03

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