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Allylic Rearrangements. XIX. Studies of the Ozonization of Allylic Systems

Young, William G. and McKinnis, Art C. and Webb, Irving D. and Roberts, John D. (1946) Allylic Rearrangements. XIX. Studies of the Ozonization of Allylic Systems. Journal of the American Chemical Society, 68 (2). pp. 293-296. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20150930-135823293

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Abstract

During the investigation of the reactions of certain allylic systems under controlled conditions it has been necessary to devise methods for the analysis of mixtures of allylic isomers, the compositions of which could not be readily determined by the fractional distillation procedures used previously. Hurd has applied the ozonolysis method to the analysis of hexenyl bromides and the results are in satisfactory agreement with those obtained by the refractometric method. We have investigated the ozonization of other types of allylic systems giving particular attention to the influence of the group X on the products obtained from isomers of the type RCH=CH-CHR’X (I) and RCHX-CH=CHR’ (II).


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http://dx.doi.org/10.1021/ja01206a042DOIArticle
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Additional Information:© 1946 American Chemical Society. Received September 27, 1945. Presented in part before the Division of Organic Chemistry at the Buffalo meeting of the American Chemical Society, September, 1942.
Issue or Number:2
Record Number:CaltechAUTHORS:20150930-135823293
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150930-135823293
Official Citation:Allylic Rearrangements. XIX. Studies of the Ozonization of Allylic Systems William G. Young, Art C. McKinnis, Irving D. Webb, and John D. Roberts Journal of the American Chemical Society 1946 68 (2), 293-296 DOI: 10.1021/ja01206a042
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:60632
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:05 Oct 2015 17:30
Last Modified:03 Oct 2019 08:59

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