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Cyclopropane Derivatives. I. Studies of the Photochemical and Thermal Chlorination of Cyclopropane

Roberts, John D. and Dirstine, Philip H. (1945) Cyclopropane Derivatives. I. Studies of the Photochemical and Thermal Chlorination of Cyclopropane. Journal of the American Chemical Society, 67 (8). pp. 1281-1283. ISSN 0002-7863. http://resolver.caltech.edu/CaltechAUTHORS:20150930-135823556

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Abstract

Gustavson has reported that the photochemical chlorination of cyclopropane gave 1, 1-dichlorocyclopropane and high-boiling compounds resulting from ring-opening reactions as the principal products. Small quantities of cyclopropyl chloride were isolated but the yields were unsatisfactory and attempts were made to prepare the monohalide by other methods. In beginning an investigation of the chemistry of cyclopropyl halides, we have studied the photochemical and thermal chlorination of cyclopropane in flow systems using conditions which were hoped to give useful yields of cyclopropyl chloride.


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http://dx.doi.org/10.1021/ja01224a020DOIArticle
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Additional Information:© 1945 American Chemical Society. Received April 23, 1945. The authors are pleased to acknowledge the aid of Drs. W. G. Young and M. J. Schlatter to this investigation. One of us (P. H. D.) wishes to thank the Dow Chemical Company for a fellowship grant in support of this work.
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Record Number:CaltechAUTHORS:20150930-135823556
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20150930-135823556
Official Citation:Cyclopropane Derivatives. I. Studies of the Photochemical and Thermal Chlorination of Cyclopropane John D. Roberts and Philip H. Dirstine Journal of the American Chemical Society 1945 67 (8), 1281-1283 DOI: 10.1021/ja01224a020
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:60633
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:02 Oct 2015 16:52
Last Modified:02 Oct 2015 16:52

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