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The reaction of butenylmagnesium bromide with acetomestiylene

Young, William G. and Roberts, John D. (1944) The reaction of butenylmagnesium bromide with acetomestiylene. Journal of the American Chemical Society, 66 (12). p. 2131. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20150930-135824582

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Abstract

In a study of the nature of the butenyl Grignard reagent it appeared that valuable information might be obtained from the composition of the butenes resulting from the enolization of ketones by butenylmagnesium bromide. Acetomesitylene was chosen for this experiment as several investigators have shown that organometallic compounds such as ethylmagnesium bromide, n-butyllithium and phenylsodium do not add to the carbonyl group of this compound but give enolization products exclusively.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja01240a512DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja01240a512PublisherArticle
Additional Information:© 1944 American Chemical Society. Received November 20, 1944.
Issue or Number:12
Record Number:CaltechAUTHORS:20150930-135824582
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150930-135824582
Official Citation:THE REACTION OF BUTENYLMAGNESIUM BROMIDE WITH ACETOMESITYLENE William G. Young and John D. Roberts Journal of the American Chemical Society 1944 66 (12), 2131-2131 DOI: 10.1021/ja01240a512
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:60637
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:30 Sep 2015 22:57
Last Modified:03 Oct 2019 08:59

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