Roberts, John D. and Young, William G. (1945) Allylic Rearrangements. XVI. The Addition of the Butenyl Grignard Reagent to Some Simple Carbonyl Compounds. Journal of the American Chemical Society, 67 (1). pp. 148-150. ISSN 0002-7863. doi:10.1021/ja01217a051. https://resolver.caltech.edu/CaltechAUTHORS:20150930-135824857
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Abstract
The nature of allylic Grignard reagents has been the subject of many investigations. Aside from those cases where the allylic double bond is included in an aromatic ring (as benzylmagnesium chloride) the structures of these substances are still open to question. For a simple primary-secondary allylic system it may be expected that the Grignard reagent will be primary (I), secondary (II) or a mixture of these forms.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1945 American Chemical Society. Received October 16, 1944. Presented before the Division of Organic Chemistry of the American Chemical Society at New York City, September, 1944. [John D. Roberts] Abbott Laboratories Research Fellow, 1943-44. | |||||||||
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| Issue or Number: | 1 | |||||||||
| DOI: | 10.1021/ja01217a051 | |||||||||
| Record Number: | CaltechAUTHORS:20150930-135824857 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150930-135824857 | |||||||||
| Official Citation: | Allylic Rearrangements. XVI. The Addition of the Butenyl Grignard Reagent to Some Simple Carbonyl Compounds John D. Roberts and William G. Young Journal of the American Chemical Society 1945 67 (1), 148-150 DOI: 10.1021/ja01217a051 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 60638 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | George Porter | |||||||||
| Deposited On: | 30 Sep 2015 21:33 | |||||||||
| Last Modified: | 10 Nov 2021 22:36 |
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