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Allylic Rearrangements. XVI. The Addition of the Butenyl Grignard Reagent to Some Simple Carbonyl Compounds

Roberts, John D. and Young, William G. (1945) Allylic Rearrangements. XVI. The Addition of the Butenyl Grignard Reagent to Some Simple Carbonyl Compounds. Journal of the American Chemical Society, 67 (1). pp. 148-150. ISSN 0002-7863. http://resolver.caltech.edu/CaltechAUTHORS:20150930-135824857

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Abstract

The nature of allylic Grignard reagents has been the subject of many investigations. Aside from those cases where the allylic double bond is included in an aromatic ring (as benzylmagnesium chloride) the structures of these substances are still open to question. For a simple primary-secondary allylic system it may be expected that the Grignard reagent will be primary (I), secondary (II) or a mixture of these forms.


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http://dx.doi.org/10.1021/ja01217a051DOIArticle
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Additional Information:© 1945 American Chemical Society. Received October 16, 1944. Presented before the Division of Organic Chemistry of the American Chemical Society at New York City, September, 1944. [John D. Roberts] Abbott Laboratories Research Fellow, 1943-44.
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Record Number:CaltechAUTHORS:20150930-135824857
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20150930-135824857
Official Citation:Allylic Rearrangements. XVI. The Addition of the Butenyl Grignard Reagent to Some Simple Carbonyl Compounds John D. Roberts and William G. Young Journal of the American Chemical Society 1945 67 (1), 148-150 DOI: 10.1021/ja01217a051
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ID Code:60638
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:30 Sep 2015 21:33
Last Modified:13 Feb 2019 18:03

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