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Solvolytic Reactivities of Nortricyclyl, Dehydronorbornyl and Norbornyl Halides. Possible Steric Requirements for Hyperconjugative Resonance

Roberts, John D. and Bennett, Winifred and Armstrong, Rose (1950) Solvolytic Reactivities of Nortricyclyl, Dehydronorbornyl and Norbornyl Halides. Possible Steric Requirements for Hyperconjugative Resonance. Journal of the American Chemical Society, 72 (8). pp. 3329-3333. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20151001-104316416

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Abstract

The present investigation is concerned with the determination and interpretation of the solvolytic reactivities of nortricyclyl (I), endo-dehydronorbornyl (II), exo-dehydronorbornyl (III), endonorbornyl (IV) and exo-norbornyl (V) halides. This series of structurally similar compounds provides an almost unique opportunity to observe the relationship between stereochemistry and solvolytic reactivities in alicyclic halides.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja01164a001DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja01164a001PublisherArticle
Additional Information:© 1950 American Chemical Society. Received June 1, 1950. Supported in part by the joint program of the Office of Naval Research and the Atomic Energy Commission.
Funders:
Funding AgencyGrant Number
Office of Naval Research (ONR)UNSPECIFIED
Atomic Energy CommissionUNSPECIFIED
Issue or Number:8
Record Number:CaltechAUTHORS:20151001-104316416
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20151001-104316416
Official Citation:Solvolytic Reactivities of Nortricyclyl, Dehydronorbornyl and Norbornyl Halides. Possible Steric Requirements for Hyperconjugative Resonance John D. Roberts, Winifred Bennett, and Rose Armstrong Journal of the American Chemical Society 1950 72 (8), 3329-3333 DOI: 10.1021/ja01164a001
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:60678
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:02 Oct 2015 15:41
Last Modified:03 Oct 2019 08:59

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