Kanamori, Keiko and Roberts, John D. and Rossman, Mitchell A. and Leonard, Nelson J. (1992) Systematic series of azacycl[3.3.3]azines of varying nitrogen content: Nitrogen-15 magnetic resonance spectra. Heteroatom Chemistry, 3 (1). pp. 19-23. ISSN 1042-7163. doi:10.1002/hc.520030105. https://resolver.caltech.edu/CaltechAUTHORS:20151002-123936830
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Abstract
Nitrogen-15 NMR spectra were obtained for a systematic series of azacycl[3.3.3]azines: 1,3,4,6,7,9-hexaaza-,1,3,4,6,7-pentaaza-,1,3,4,6-tetraaza-, 1,3,4,6,8-pentaaza-, and 1,3,6-triazacycl[3.3.3]azine. The magnetic resonance data were compared with other physical and spectroscopic properties available for the series relative to the diminishing number of peripheral nitrogens in alternating positions. The properties of 1,3,4,6,8-pentaazacycl[3.3.3]azine, which has a peripheral 1,4-diazine-type nitrogen, are distinct from those of the rest of the series.
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| Additional Information: | © 1992 VCH Publishers, Inc. Received 25 June 1991. This work was supported at the University of Illinois by Research Grant No. CHE 81-21796 from the National Science Foundation and at the California Institute of Technology by the National Science Foundation and by the U.S. Public Health Service, Research Grant No. GM 11072 from the Institute of General Medical Sciences. We thank S. Urano and P. R. LeBreton for permission to quote from their preliminary SCS ST0-3G calculations performed with the GAUSSIAN 80 program. | |||||||||
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| Issue or Number: | 1 | |||||||||
| DOI: | 10.1002/hc.520030105 | |||||||||
| Record Number: | CaltechAUTHORS:20151002-123936830 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151002-123936830 | |||||||||
| Official Citation: | Kanamori, K., Roberts, J. D., Rossman, M. A. and Leonard, N. J. (1992), Systematic series of azacycl[3.3.3]azines of varying nitrogen content: Nitrogen-15 magnetic resonance spectra. Heteroatom Chem., 3: 19–23. doi: 10.1002/hc.520030105 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 60716 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 05 Oct 2015 16:28 | |||||||||
| Last Modified: | 10 Nov 2021 22:38 |
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