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Isotope Scrambling with ^(15)N-Labeled Azide Ion and p-Toluenesulfonyl Azide

Casewit, Carla and Wenninger, J. and Roberts, John D. (1981) Isotope Scrambling with ^(15)N-Labeled Azide Ion and p-Toluenesulfonyl Azide. Journal of the American Chemical Society, 103 (20). pp. 6248-6249. ISSN 0002-7863. http://resolver.caltech.edu/CaltechAUTHORS:20151006-073240179

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Abstract

p-Toluenesulfonyl azide (1) reacts with azide ion in dimethyl sulfoxide solution to form p-toluenesulfinate anion and dinitrogen (eq 1, Ts = 4-CH_3C_6H_4SO_2).^2 For a determination of whether TsN_3+N_3 → Ts + 3N_2 (1) or not there are solvent effects on this reaction, it has been studied in other solvents by ^(15)N NMR spectroscopy using potassium azide-1,3-^(15)N_1 (99%) as a tracer.


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http://dx.doi.org/10.1021/ja00410a058DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja00410a058PublisherArticle
Alternate Title:Isotope scrambling with nitrogen-15-labeled azide ion and p-toluenesulfonyl azide
Additional Information:© 1981 American Chemical Society. Received April 2, 1981. Supported by the National Science Foundation. IBM Graduate Fellow 1979-1980. DAAD Postdoctoral Fellow, 1980-1981.
Funders:
Funding AgencyGrant Number
NSFUNSPECIFIED
IBM Graduate FellowUNSPECIFIED
Deutscher Akademischer Austauschdienst (DAAD)UNSPECIFIED
Record Number:CaltechAUTHORS:20151006-073240179
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20151006-073240179
Official Citation:Isotope scrambling with nitrogen-15-labeled azide ion and p-toluenesulfonyl azide Carla Casewit, J. Wenninger, and John D. Roberts Journal of the American Chemical Society 1981 103 (20), 6248-6249 DOI: 10.1021/ja00410a058
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:60794
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:06 Oct 2015 21:34
Last Modified:06 Oct 2015 21:34

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