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The ^(119)Sn-^(13)C and ^(119)Sn-^1H Couplings for Methyl Derivatives of tin in Various Solvents

Petrosyan, V. S. and Permin, A. B. and Reutov, O. A. and Roberts, John D. (1980) The ^(119)Sn-^(13)C and ^(119)Sn-^1H Couplings for Methyl Derivatives of tin in Various Solvents. Journal of Magnetic Resonance, 40 (3). pp. 511-518. ISSN 1090-7807. doi:10.1016/0022-2364(80)90010-4. https://resolver.caltech.edu/CaltechAUTHORS:20151006-132046054

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Abstract

The spin-spin coupling constants |1J(^(119)Sn-^(13)C)| and |2J(^(119)Sn-^1H)| have been obtained from ^(13)C and ^1H NMR spectra of (CH_3)_n SnHal_(4−n) (n =1-4; Hat = Cl, Br) in various solvents (CCl_4, benzene, nitrobenzene, CD_3CN, acetone-d_6, dimethylformamide-d_7, dimethyl sulfoxide-d_6, pyridine, hexamethylphosphoramide). The data show that the relations between these constants as a function of solvent are not linear, and this indicates that other contributions besides Fermi contact terms are important in determining ^(119)Sn-^(13)C couplings.


Item Type:Article
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http://dx.doi.org/10.1016/0022-2364(80)90010-4DOIArticle
http://www.sciencedirect.com/science/article/pii/0022236480900104PublisherArticle
Additional Information:© 1980 Published by Elsevier Inc. Received January 22, 1979; revised July 17, 1979. Supported by the National Science Foundation, and by the Public Health Service, Research Grant No. GM-11072 from the Division of General Medical Sciences.
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U.S. Public Health Service (USPHS)GM-11072
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Caltech Gates and Crellin Laboratories of Chemistry5960
Issue or Number:3
DOI:10.1016/0022-2364(80)90010-4
Record Number:CaltechAUTHORS:20151006-132046054
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20151006-132046054
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:60812
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:06 Oct 2015 23:00
Last Modified:10 Nov 2021 22:39

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