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Growth of ZSM-5 films on alumina and other surfaces

Lai, Re and Yan, Yushan and Gavalas, George R. (2000) Growth of ZSM-5 films on alumina and other surfaces. Microporous and Mesoporous Materials, 37 (1-2). pp. 9-19. ISSN 1387-1811. https://resolver.caltech.edu/CaltechAUTHORS:20151006-150213451

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Abstract

Growth of ZSM-5 films on porous α-Al2O3 and other substrates was studied with the main focus on the effect of the substrate on surface gel formation and zeolitization. The films formed on the substrate and the powders that settled at the bottom of the autoclave were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD). Adsorption of Ar and iso-butane was used to estimate the crystalline fraction of the product formed on and in the pores of the substrate. The presence of alumina substrates accelerated bulk zeolitization for certain solution compositions. Aluminum added to the solution had dual effects, to induce gel layer formation on the substrate surface and to retard zeolitization of that layer as well as retard zeolitization in the bulk of the solution.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1016/S1387-1811(99)00188-2DOIArticle
http://www.sciencedirect.com/science/article/pii/S1387181199001882PublisherArticle
ORCID:
AuthorORCID
Gavalas, George R.0000-0003-1468-6835
Additional Information:© 2000 Elsevier. Received 18 July 1999; accepted for publication 26 September 1999. This study was funded by NSF Grant CTS 9504901 and by Chevron Research and Technology Co.
Funders:
Funding AgencyGrant Number
NSFCTS 9504901
Chevron Research and Technology Co.UNSPECIFIED
Subject Keywords:Aluminosilicate gels; MFI; Zeolite film; Zeolite membrane; ZSM-5
Issue or Number:1-2
Record Number:CaltechAUTHORS:20151006-150213451
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20151006-150213451
Official Citation:Re Lai, Yushan Yan, George R. Gavalas, Growth of ZSM-5 films on alumina and other surfaces, Microporous and Mesoporous Materials, Volume 37, Issues 1–2, May 2000, Pages 9-19, ISSN 1387-1811, http://dx.doi.org/10.1016/S1387-1811(99)00188-2. (http://www.sciencedirect.com/science/article/pii/S1387181199001882)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:60829
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:07 Oct 2015 18:13
Last Modified:03 Oct 2019 09:01

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