Schuster, Ingeborg I. and Roberts, John D. (1980) Proximity Effects on Nitrogen-15 Chemical Shifts of 8-Substituted 1-Nitronaphthalenes and 1-Naphthylamines. Journal of Organic Chemistry, 45 (2). pp. 284-287. ISSN 0022-3263. doi:10.1021/jo01290a016. https://resolver.caltech.edu/CaltechAUTHORS:20151007-073141214
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Abstract
^(15)N chemical shifts of several substituted 1-nitronaphthalenes and 8-substituted 1-naphthylamines have been determined and, in general, the substituent effects are unexpectedly small. The high-field shift of the amine nitrogen of 8-nitro-1-aminonaphthalene may indicate a degree of σ complexing between the amino group and the proximate substituents of the type suggested by Dunitz. The smallness of the other substituent effects may be the result of mutual cancellation of opposing larger effects.
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| Additional Information: | © 1980 American Chemical Society. Received June 4, 1979. Supported by the National Science Foundation and by the Public Health Service, Research Grant No. GM-11072 from the Division of General Medical Sciences. | |||||||||
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| Issue or Number: | 2 | |||||||||
| DOI: | 10.1021/jo01290a016 | |||||||||
| Record Number: | CaltechAUTHORS:20151007-073141214 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151007-073141214 | |||||||||
| Official Citation: | Proximity effects on nitrogen-15 chemical shifts of 8-substituted 1-nitronaphthalenes and 1-naphthylamines Ingeborg I. Schuster and John D. Roberts The Journal of Organic Chemistry 1980 45 (2), 284-287 DOI: 10.1021/jo01290a016 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 60835 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 07 Oct 2015 15:50 | |||||||||
| Last Modified: | 10 Nov 2021 22:40 |
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