Botto, Robert E. and Roberts, John D. (1977) Nitrogen-15 Magnetic Resonance Spectroscopy. Natural-Abundance Nitrogen-15 Spectra of Some 2-Amino-2-deoxy-D-hexose Derivatives. Journal of Organic Chemistry, 42 (13). pp. 2247-2249. ISSN 0022-3263. doi:10.1021/jo00433a012. https://resolver.caltech.edu/CaltechAUTHORS:20151008-115811190
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Abstract
The nitrogen-15 nuclear magnetic resonance spectra of some 2-amino-2-deoxj D-hexose drochlorides and 2-acetamido-2-deoxy-D-hexoses and N-benzoyl-D-glucosamine are reported. The differences in chemical shifts for the various hexopyranose structures are discussed in terms of steric, stereoelectronic, and hydrogen-bonding effects. These model compounds were used to study substituent effects related to amino sugar containing polysaccharides and antibiotics.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1977 American Chemical Society. Received September 28, 1976. Supported by the Public Health Service, Research Grant GM-11072, from the Division of General Medical Sciences, and by the National Science Foundation. | |||||||||
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| Issue or Number: | 13 | |||||||||
| DOI: | 10.1021/jo00433a012 | |||||||||
| Record Number: | CaltechAUTHORS:20151008-115811190 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151008-115811190 | |||||||||
| Official Citation: | Nitrogen-15 magnetic resonance spectroscopy. Natural-abundance nitrogen-15 spectra of some 2-amino-2-deoxy-D-hexose derivatives Robert E. Botto and John D. Roberts The Journal of Organic Chemistry 1977 42 (13), 2247-2249 DOI: 10.1021/jo00433a012 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 60911 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 11 Oct 2015 11:05 | |||||||||
| Last Modified: | 10 Nov 2021 22:41 |
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