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Carbon-13 Nuclear Magnetic Resonance Spectroscopy. Charge-Transfer Complexes

Griffith, Ronald C. and Grant, David M. and Roberts, John D. (1975) Carbon-13 Nuclear Magnetic Resonance Spectroscopy. Charge-Transfer Complexes. Journal of Organic Chemistry, 40 (25). pp. 3726-3729. ISSN 0022-3263. http://resolver.caltech.edu/CaltechAUTHORS:20151008-153158525

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Abstract

High-resolution ^(13)C pulse Fourier transform nuclear magnetic resonance has been used to study the effects of charge-transfer complexation between trinitrobenzene and aromatic donor molecules: benzene, mesitylene, naphthalene, and anthracene. Plots of the chemical shifts of the donor carbons as a function of acceptor concentration allows the ready determination of the association constants, K_(AD), and the bound shifts of the donor carbons in the pure 1:1 complexes, Δ_0. The Δ_0 values so obtained indicate that diamagnetic ring anisotropy and transfer of charge are as phenomenologically important to ^(13)C as to ^1H NMR for aromatic molecules.


Item Type:Article
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http://dx.do.org/10.1021/jo00913a023DOIArticle
http://pubs.acs.org/doi/abs/10.1021/jo00913a023PublisherArticle
Additional Information:© 1975 American Chemical Society. Received March 25, 1975. We are pleased to acknowledge the assistance of Dr. Stefan Berger in writing the computer program, and for stimulating discussions regarding this work. Supported by the National Science Foundation, and by the Public Health Service, Research Grant GM-11072, from the Division of General Medical Sciences; Sherman Fairchild Distinguished Scholar at the California Institute of Technology, 1973-1974, on sabbatical leave from the Department of Chemistry, University of Utah.
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NSFUNSPECIFIED
U.S. Public Health Service (USPHS)GM-11072
Sherman Fairchild FoundationUNSPECIFIED
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Caltech Gates and Crellin Laboratories of Chemistry5064
Record Number:CaltechAUTHORS:20151008-153158525
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20151008-153158525
Official Citation:Carbon-13 nuclear magnetic resonance spectroscopy. Charge-transfer complexes Ronald C. Griffith, David M. Grant, and John D. Roberts The Journal of Organic Chemistry 1975 40 (25), 3726-3729 DOI: 10.1021/jo00913a023
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:60921
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:10 Oct 2015 02:55
Last Modified:10 Oct 2015 02:55

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