CaltechAUTHORS
  A Caltech Library Service

Nuclear Magnetic Resonance Spectroscopy. ^(13)C-^(15)N Coupling Constants as a Conformational Probe?

Berger, Stefan and Roberts, John D. (1974) Nuclear Magnetic Resonance Spectroscopy. ^(13)C-^(15)N Coupling Constants as a Conformational Probe? Journal of the American Chemical Society, 96 (21). pp. 6757-6759. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20151008-153200440

Full text is not posted in this repository. Consult Related URLs below.

Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20151008-153200440

Abstract

There have been several attempts to explain the variation in ^(13)C-^(l5)N coupling constants with the stereochemical orientation of the carbons with respect to the nitrogen lone pairs. Most of the substances investigated so far, however, have the possibility of averaging of coupling constants due to bond rotation and/or nitrogen inversion. The only relatively rigid substances looked at have had aromatic nitrogen, and, with these, other effects are expected to play a role.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/http://pubs.acs.org/doi/abs/10.1021/ja00828a036`DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja00828a036PublisherArticle
Alternate Title:Nuclear magnetic resonance spectroscopy. Carbon-13-nitrogen-15 coupling constants as a conformational probe
Additional Information:© 1974 American Chemical Society. Received July 26, 1974. Supported by the National Science Foundation and by the Public Health Service, Research Grant No, GM-11072, from the Division of General Medical Sciences.
Funders:
Funding AgencyGrant Number
NSFUNSPECIFIED
U.S. Public Health Service (USPHS)GM-11072
Deutsche Forschungsgemeinschaft (DFG)UNSPECIFIED
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Caltech Gates and Crellin Laboratories of Chemistry4930
Issue or Number:21
Record Number:CaltechAUTHORS:20151008-153200440
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20151008-153200440
Official Citation:Nuclear magnetic resonance spectroscopy. Carbon-13-nitrogen-15 coupling constants as a conformational probe Stefan Berger and John D. Roberts Journal of the American Chemical Society 1974 96 (21), 6757-6759 DOI: 10.1021/ja00828a036
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:60928
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:10 Oct 2015 02:59
Last Modified:03 Oct 2019 09:02

Repository Staff Only: item control page