Berger, Stefan and Roberts, John D. (1974) Nuclear Magnetic Resonance Spectroscopy. ^(13)C-^(15)N Coupling Constants as a Conformational Probe? Journal of the American Chemical Society, 96 (21). pp. 6757-6759. ISSN 0002-7863. doi:10.1021/ja00828a036`. https://resolver.caltech.edu/CaltechAUTHORS:20151008-153200440
Full text is not posted in this repository. Consult Related URLs below.
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20151008-153200440
Abstract
There have been several attempts to explain the variation in ^(13)C-^(l5)N coupling constants with the stereochemical orientation of the carbons with respect to the nitrogen lone pairs. Most of the substances investigated so far, however, have the possibility of averaging of coupling constants due to bond rotation and/or nitrogen inversion. The only relatively rigid substances looked at have had aromatic nitrogen, and, with these, other effects are expected to play a role.
| Item Type: | Article | |||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Related URLs: |
| |||||||||
| Alternate Title: | Nuclear magnetic resonance spectroscopy. Carbon-13-nitrogen-15 coupling constants as a conformational probe | |||||||||
| Additional Information: | © 1974 American Chemical Society. Received July 26, 1974. Supported by the National Science Foundation and by the Public Health Service, Research Grant No, GM-11072, from the Division of General Medical Sciences. | |||||||||
| Funders: |
| |||||||||
| Other Numbering System: |
| |||||||||
| Issue or Number: | 21 | |||||||||
| DOI: | 10.1021/ja00828a036` | |||||||||
| Record Number: | CaltechAUTHORS:20151008-153200440 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151008-153200440 | |||||||||
| Official Citation: | Nuclear magnetic resonance spectroscopy. Carbon-13-nitrogen-15 coupling constants as a conformational probe Stefan Berger and John D. Roberts Journal of the American Chemical Society 1974 96 (21), 6757-6759 DOI: 10.1021/ja00828a036 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 60928 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 10 Oct 2015 02:59 | |||||||||
| Last Modified: | 10 Nov 2021 22:41 |
Repository Staff Only: item control page
