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Nuclear Magnetic Resonance Spectroscopy. Carbon-13 Chemical Shifts of Chlorinated Organic Compounds

Hawkes, Geoffrey E. and Smith, Robert A. and Roberts, John D. (1974) Nuclear Magnetic Resonance Spectroscopy. Carbon-13 Chemical Shifts of Chlorinated Organic Compounds. Journal of Organic Chemistry, 39 (9). pp. 1276-1290. ISSN 0022-3263. doi:10.1021/jo00923a026.

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The ^(13)C chemical shifts of a variety of perchlorocarbons, their hydrogen-substituted derivatives, and chlorocarbon ketones have been determined and assigned to specific carbons by high-resolution nuclear magnetic resonance spectroscopy. The assignment of ^(13)C resonances for these substances was often aided by ^(13)-^1H couplings and Overhauser enhancements observed in the carbon spectra of the hydrogen-substituted derivatives. Correlations between ^(13)C chemical shifts and structure were found for simple molecules and these correlations appear to provide the possibility of reasonable structural assignments for complex perchlorocarbons.

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Additional Information:© 1974 American Chemical Society. Received March 6, 1973. Supported by the National Science Foundation, and by the Public Health Service, Research Grant No. GM-11072 from the Division of General Medical Services. Some of the data in this paper has been reported earlier by V. Mark and E. D. Well, J, Org. Chem.,36, 676 (1971). NATO Postdoctoral Fellow, 1970-1972.
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U.S. Public Health Service (USPHS)GM-11072
North Atlantic Treaty Organization (NATO)UNSPECIFIED
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Caltech Gates and Crellin Laboratories of Chemistry4654
Issue or Number:9
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Official Citation:Nuclear magnetic resonance spectroscopy. Carbon-13 chemical shifts of chlorinated organic compounds Geoffrey E. Hawkes, Robert A. Smith, and John D. Roberts The Journal of Organic Chemistry 1974 39 (9), 1276-1290 DOI: 10.1021/jo00923a026
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:60930
Deposited By: Ruth Sustaita
Deposited On:10 Oct 2015 01:56
Last Modified:10 Nov 2021 22:41

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