Bercaw, John E. and Rosenberg, Edward and Roberts, John D. (1974) ^1H, ^(13)C, and ^(15)N Nuclear Magnetic Resonance Studies of a Dinitrogen Complex of Permethyltitanocene. Evidence for Molecular Nitrogen Coordinated “Edge-on” to a Transition Metal. Journal of the American Chemical Society, 96 (2). pp. 612-614. ISSN 0002-7863. doi:10.1021/ja00809a063. https://resolver.caltech.edu/CaltechAUTHORS:20151008-153202191
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Abstract
In connection with the current interest in transition metal dinitrogen complexes and their possible roles in nitrogen-fixing reaction systems, we have obtained results which bear on the structure of a titanium dinitrogen complex in solution. We report here successful application of ^(15)N nmr spectroscopy to studies of a transition metal dinitrogen complex which provides a potentially powerful technique for elucidation of the structure of such complexes.
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| Additional Information: | © 1974 American Chemical Society. Received January 23, 1974. This work has been supported by the Ford Motor Co., the Public Health Service through Research Grant No. GM-11072, Division of Medical Sciences, and by the National Science Foundation. We wish to thank Professors H. B. Gray and J. G. Gordon for helpful discussions. | |||||||||
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| Issue or Number: | 2 | |||||||||
| DOI: | 10.1021/ja00809a063 | |||||||||
| Record Number: | CaltechAUTHORS:20151008-153202191 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151008-153202191 | |||||||||
| Official Citation: | Proton, carbon-13, and nitrogen-15 nuclear magnetic resonance studies of a dinitrogen complex of permethyltitanocene. Evidence for molecular nitrogen coordinated edge-on to a transition metal John E. Bercaw, Edward Rosenberg, and John D. Roberts Journal of the American Chemical Society 1974 96 (2), 612-614 DOI: 10.1021/ja00809a063 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 60934 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 10 Oct 2015 01:43 | |||||||||
| Last Modified: | 10 Nov 2021 22:41 |
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