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^1H, ^(13)C, and ^(15)N Nuclear Magnetic Resonance Studies of a Dinitrogen Complex of Permethyltitanocene. Evidence for Molecular Nitrogen Coordinated “Edge-on” to a Transition Metal

Bercaw, John E. and Rosenberg, Edward and Roberts, John D. (1974) ^1H, ^(13)C, and ^(15)N Nuclear Magnetic Resonance Studies of a Dinitrogen Complex of Permethyltitanocene. Evidence for Molecular Nitrogen Coordinated “Edge-on” to a Transition Metal. Journal of the American Chemical Society, 96 (2). pp. 612-614. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20151008-153202191

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Abstract

In connection with the current interest in transition metal dinitrogen complexes and their possible roles in nitrogen-fixing reaction systems, we have obtained results which bear on the structure of a titanium dinitrogen complex in solution. We report here successful application of ^(15)N nmr spectroscopy to studies of a transition metal dinitrogen complex which provides a potentially powerful technique for elucidation of the structure of such complexes.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja00809a063DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja00809a063PublisherArticle
Additional Information:© 1974 American Chemical Society. Received January 23, 1974. This work has been supported by the Ford Motor Co., the Public Health Service through Research Grant No. GM-11072, Division of Medical Sciences, and by the National Science Foundation. We wish to thank Professors H. B. Gray and J. G. Gordon for helpful discussions.
Funders:
Funding AgencyGrant Number
Ford Motor CompanyUNSPECIFIED
U.S. Public Health Service (USPHS)GM-11072
NSFUNSPECIFIED
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Caltech Noyes and Crellin Laboratories of Chemistry4765
Issue or Number:2
Record Number:CaltechAUTHORS:20151008-153202191
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20151008-153202191
Official Citation:Proton, carbon-13, and nitrogen-15 nuclear magnetic resonance studies of a dinitrogen complex of permethyltitanocene. Evidence for molecular nitrogen coordinated edge-on to a transition metal John E. Bercaw, Edward Rosenberg, and John D. Roberts Journal of the American Chemical Society 1974 96 (2), 612-614 DOI: 10.1021/ja00809a063
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:60934
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:10 Oct 2015 01:43
Last Modified:03 Oct 2019 09:02

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