Dorman, Douglas E. and Jautelat, Manfred and Roberts, John D. (1973) Carbon-13 Nuclear Magnetic Resonance Spectroscopy. Spectra of the Linear Alkynes. Journal of Organic Chemistry, 38 (5). pp. 1026-1030. ISSN 0022-3263. doi:10.1021/jo00945a034. https://resolver.caltech.edu/CaltechAUTHORS:20151009-133524169
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Abstract
The ^(13)C chemical shifts of a selection of linear alkynes are collected and correlated with structure. A system of empirical rules by which the ^(13)C nuclear magnetic resonance spectra of such compounds can be predicted is derived. The failure of the current point-dipole approximation to predict correctly the shifts due to the anisotropy of the triple bond is discussed.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1972 American Chemical Society. Received July 24, 1971. Supported by the National Science Foundation. | |||||||||
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| Issue or Number: | 5 | |||||||||
| DOI: | 10.1021/jo00945a034 | |||||||||
| Record Number: | CaltechAUTHORS:20151009-133524169 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151009-133524169 | |||||||||
| Official Citation: | Carbon-13 nuclear magnetic resonance spectroscopy. Spectra of the linear alkynes Douglas E. Dorman, Manfred Jautelat, and John D. Roberts The Journal of Organic Chemistry 1973 38 (5), 1026-1030 DOI: 10.1021/jo00945a034 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 60948 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 15 Oct 2015 23:35 | |||||||||
| Last Modified: | 10 Nov 2021 22:42 |
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