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Carbon-13 Nuclear Magnetic Resonance Spectroscopy. Spectra of the Linear Alkynes

Dorman, Douglas E. and Jautelat, Manfred and Roberts, John D. (1973) Carbon-13 Nuclear Magnetic Resonance Spectroscopy. Spectra of the Linear Alkynes. Journal of Organic Chemistry, 38 (5). pp. 1026-1030. ISSN 0022-3263. doi:10.1021/jo00945a034.

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The ^(13)C chemical shifts of a selection of linear alkynes are collected and correlated with structure. A system of empirical rules by which the ^(13)C nuclear magnetic resonance spectra of such compounds can be predicted is derived. The failure of the current point-dipole approximation to predict correctly the shifts due to the anisotropy of the triple bond is discussed.

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Additional Information:© 1972 American Chemical Society. Received July 24, 1971. Supported by the National Science Foundation.
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Caltech Gates and Crellin Laboratories of Chemistry4509
Issue or Number:5
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Official Citation:Carbon-13 nuclear magnetic resonance spectroscopy. Spectra of the linear alkynes Douglas E. Dorman, Manfred Jautelat, and John D. Roberts The Journal of Organic Chemistry 1973 38 (5), 1026-1030 DOI: 10.1021/jo00945a034
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:60948
Deposited By: Ruth Sustaita
Deposited On:15 Oct 2015 23:35
Last Modified:10 Nov 2021 22:42

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