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Nuclear Magnetic Resonance Spectroscopy. Hindered Rotation about the Carbon-Phosphorus Bond in tert-Butyldichlorophosphine

Roberts, J. B. and Roberts, John D. (1972) Nuclear Magnetic Resonance Spectroscopy. Hindered Rotation about the Carbon-Phosphorus Bond in tert-Butyldichlorophosphine. Journal of the American Chemical Society, 94 (14). pp. 4902-4904. ISSN 0002-7863. http://resolver.caltech.edu/CaltechAUTHORS:20151009-133525849

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Abstract

The barrier to rotation about the C-P bond in tert-butyldichlorophosphine has been derived from a line-shape analysis of the proton nmr spectrum as a function of temperature. The ^3J_(PCCH) coupling constants are different for the two kinds of methyl protons, This difference suggests an influence of the bond orientation about the phosphorus-carbon bond on ^3J_(PCCH) for three-coordinate phosphorus compounds.


Item Type:Article
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http://dx.doi.org/10.1021/ja00769a018DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja00769a018PublisherArticle
Additional Information:© 1972 American Chemical Society. Received September 24, 1971. Supported by the National Science Foundation.
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Caltech Gates and CrelIin Laboratories of Chemistry4335
Record Number:CaltechAUTHORS:20151009-133525849
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20151009-133525849
Official Citation:Nuclear magnetic resonance spectroscopy. Hindered rotation about the carbon-phosphorus bond in tert-butyldichlorophosphine J. B. Robert and John D. Roberts Journal of the American Chemical Society 1972 94 (14), 4902-4904 DOI: 10.1021/ja00769a018
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:60954
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:15 Oct 2015 23:28
Last Modified:15 Oct 2015 23:28

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