A Caltech Library Service

Nuclear Magnetic Resonance Spectroscopy. Hindered Rotation about the Carbon-Phosphorus Bond in tert-Butyldichlorophosphine

Roberts, J. B. and Roberts, John D. (1972) Nuclear Magnetic Resonance Spectroscopy. Hindered Rotation about the Carbon-Phosphorus Bond in tert-Butyldichlorophosphine. Journal of the American Chemical Society, 94 (14). pp. 4902-4904. ISSN 0002-7863. doi:10.1021/ja00769a018.

Full text is not posted in this repository. Consult Related URLs below.

Use this Persistent URL to link to this item:


The barrier to rotation about the C-P bond in tert-butyldichlorophosphine has been derived from a line-shape analysis of the proton nmr spectrum as a function of temperature. The ^3J_(PCCH) coupling constants are different for the two kinds of methyl protons, This difference suggests an influence of the bond orientation about the phosphorus-carbon bond on ^3J_(PCCH) for three-coordinate phosphorus compounds.

Item Type:Article
Related URLs:
URLURL TypeDescription
Additional Information:© 1972 American Chemical Society. Received September 24, 1971. Supported by the National Science Foundation.
Funding AgencyGrant Number
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Caltech Gates and CrelIin Laboratories of Chemistry4335
Issue or Number:14
Record Number:CaltechAUTHORS:20151009-133525849
Persistent URL:
Official Citation:Nuclear magnetic resonance spectroscopy. Hindered rotation about the carbon-phosphorus bond in tert-butyldichlorophosphine J. B. Robert and John D. Roberts Journal of the American Chemical Society 1972 94 (14), 4902-4904 DOI: 10.1021/ja00769a018
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:60954
Deposited By: Ruth Sustaita
Deposited On:15 Oct 2015 23:28
Last Modified:10 Nov 2021 22:42

Repository Staff Only: item control page