Roberts, J. B. and Roberts, John D. (1972) Nuclear Magnetic Resonance Spectroscopy. Hindered Rotation about the Carbon-Phosphorus Bond in tert-Butyldichlorophosphine. Journal of the American Chemical Society, 94 (14). pp. 4902-4904. ISSN 0002-7863. doi:10.1021/ja00769a018. https://resolver.caltech.edu/CaltechAUTHORS:20151009-133525849
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Abstract
The barrier to rotation about the C-P bond in tert-butyldichlorophosphine has been derived from a line-shape analysis of the proton nmr spectrum as a function of temperature. The ^3J_(PCCH) coupling constants are different for the two kinds of methyl protons, This difference suggests an influence of the bond orientation about the phosphorus-carbon bond on ^3J_(PCCH) for three-coordinate phosphorus compounds.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1972 American Chemical Society. Received September 24, 1971. Supported by the National Science Foundation. | |||||||||
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| Issue or Number: | 14 | |||||||||
| DOI: | 10.1021/ja00769a018 | |||||||||
| Record Number: | CaltechAUTHORS:20151009-133525849 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151009-133525849 | |||||||||
| Official Citation: | Nuclear magnetic resonance spectroscopy. Hindered rotation about the carbon-phosphorus bond in tert-butyldichlorophosphine J. B. Robert and John D. Roberts Journal of the American Chemical Society 1972 94 (14), 4902-4904 DOI: 10.1021/ja00769a018 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 60954 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 15 Oct 2015 23:28 | |||||||||
| Last Modified: | 10 Nov 2021 22:42 |
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