Noe, Eric A. and Roberts, John D. (1972) Nuclear Magnetic Resonance Spectroscopy. Ring Inversion in 1,1 -Difluorocyclodecane. Journal of the American Chemical Society, 94 (6). pp. 2020-2026. ISSN 0002-7863. doi:10.1021/ja00761a039. https://resolver.caltech.edu/CaltechAUTHORS:20151009-133527182
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Abstract
Rates of ring inversion of 1,1-difluorocyclodecane were obtained from line-shape changes in the low-temperature ^(19)F nmr spectra. At -135º, the free energy of activation was 5.7 kcal/mol. The results are interpreted in terms of a boat-chair-boat conformation. Possible pathways for effecting ring inversion are discussed.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1972 American Chemical Society. Received July 1, 1971. Supported by the National Science Foundation. Summer National Science Foundation Fellow, 1966 and 1968; National Defense Education Act Trainee, 1968-1969. | |||||||||
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| Issue or Number: | 6 | |||||||||
| DOI: | 10.1021/ja00761a039 | |||||||||
| Record Number: | CaltechAUTHORS:20151009-133527182 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151009-133527182 | |||||||||
| Official Citation: | Nuclear magnetic resonance spectroscopy. Ring inversion in 1,1-difluorocyclodecane Eric A. Noe and John D. Roberts Journal of the American Chemical Society 1972 94 (6), 2020-2026 DOI: 10.1021/ja00761a039 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 60959 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 15 Oct 2015 21:37 | |||||||||
| Last Modified: | 10 Nov 2021 22:42 |
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