CaltechAUTHORS
  A Caltech Library Service

Nuclear Magnetic Resonance Spectroscopy. Effect of N,N,N',N'-Tetramethylethylenediamine on the Schlenk Equilibrium of Ethylmagnesium Bromide

Roberts, John D. and Magnuson, J. A. (1972) Nuclear Magnetic Resonance Spectroscopy. Effect of N,N,N',N'-Tetramethylethylenediamine on the Schlenk Equilibrium of Ethylmagnesium Bromide. Journal of Organic Chemistry, 37 (1). pp. 133-135. ISSN 0022-3263. http://resolver.caltech.edu/CaltechAUTHORS:20151009-133527458

Full text is not posted in this repository. Consult Related URLs below.

Use this Persistent URL to link to this item: http://resolver.caltech.edu/CaltechAUTHORS:20151009-133527458

Abstract

The composition of Grignard reagents has been studied extensively by nuclear magnetic resonance spectroscopy and other physical techniques. Recently Parris and Ashby using nmr spectroscopy, observed both dialkyl- and alkylmagnesium species in Grignard solutions from methyl and tert-butyl halides. Earlier Evans and coworkers5 had observed diarylmagnesium and arylmagnesium halides by both fluorine and proton magnetic resonance. We wish to report the observation of diethylmagnesium and ethylmagnesium bromide in tetrahydrofuran solutions containing N,N,N',N'-tetramethylethylenediamine.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/jo00966a036DOIArticle
http://pubs.acs.org/doi/abs/10.1021/jo00966a036PublisherArticle
Additional Information:© 1972 American Chemical Society. Received April 7, 1971. Taken from the Ph.D. Dissertation of J. A Magnuson, 1968. Supported by the National Science Foundation. National Defense Education Act Fellow, 1965-1967.
Funders:
Funding AgencyGrant Number
NSFUNSPECIFIED
National Defense Education ActUNSPECIFIED
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Caltech Gates and Crellin Laboratories of Chemistry4191
Record Number:CaltechAUTHORS:20151009-133527458
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20151009-133527458
Official Citation:Nuclear magnetic resonance spectroscopy. Effect of N,N,N,',N'-tetramethylethylenediamine on the Schlenk equilibrium of ethylmagnesium bromide John D. Roberts and J. A. Magnuson The Journal of Organic Chemistry 1972 37 (1), 133-135 DOI: 10.1021/jo00966a036
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:60960
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:15 Oct 2015 21:48
Last Modified:15 Oct 2015 21:48

Repository Staff Only: item control page