Griffith, Dean L. and Olson, Bryon L. and Roberts, John D. (1971) Magnetic Nonequivalence in the Low-Temperature Nuclear Magnetic Resonance Spectra of N-benzyl-N-Methylhydroxylamine and N-Benzyl-N-methylchloramine. Journal of the American Chemical Society, 93 (7). pp. 1648-1649. ISSN 0002-7863. doi:10.1021/ja00736a013. https://resolver.caltech.edu/CaltechAUTHORS:20151012-133439627
Full text is not posted in this repository. Consult Related URLs below.
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20151012-133439627
Abstract
Reinvestigation of the low-temperature nmr spectra of N-benzyl-N-methylhydroxylamine and N-benzyl-N-methylchloramine in acetone-d_6 at 100 MHz has revealed magnetic nonequivalence. The slow process with the N-chloro compound must be nitrogen inversion. The fact that, in acetone-d_6 N-benzyl-N-methylhydroxylamine undergoes degenerate racemization more slowly than N-benzyl-O,N-dimethylhydroxylamine supports the hypothesis that inversion of nitrogen is slower than the rate of rotation about the N-O bond in these compounds.
| Item Type: | Article | |||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Related URLs: |
| |||||||||
| Additional Information: | © 1971 American Chemical Society. Received July 6, 1970. Supported by the National Science Foundation. | |||||||||
| Funders: |
| |||||||||
| Other Numbering System: |
| |||||||||
| Issue or Number: | 7 | |||||||||
| DOI: | 10.1021/ja00736a013 | |||||||||
| Record Number: | CaltechAUTHORS:20151012-133439627 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151012-133439627 | |||||||||
| Official Citation: | Magnetic nonequivalence in the low-temperature nuclear magnetic resonance spectra of N-benzyl-N-methylhydroxylamine and N-benzyl-N-methylchloramine Dean L. Griffith, Bryon L. Olson, and John D. Roberts Journal of the American Chemical Society 1971 93 (7), 1648-1649 DOI: 10.1021/ja00736a013 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 60996 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 15 Oct 2015 04:06 | |||||||||
| Last Modified: | 10 Nov 2021 22:42 |
Repository Staff Only: item control page
