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Ring Inversion of Perfluoro-1,4-dithiane

Anderson, James Edgar and Davis, Donald Robert and Roberts, John D. (1970) Ring Inversion of Perfluoro-1,4-dithiane. Journal of Organic Chemistry, 35 (4). pp. 1195-1196. ISSN 0022-3263. https://resolver.caltech.edu/CaltechAUTHORS:20151013-111509610

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Abstract

Interconversion of chair conformations of six-membered rings containing two identical heteroatoms has been much studied by the nmr method, with the exception of the 1,4-dithiane system. The results so far obtained for 1,2- and 1,3-dithianes in comparison with those of dioxanes and the corresponding diaza systems suggest that this barrier should be readily measureable by the nmr method. We are concerned here with the ring inversion of octafluoro-1,4-dithiane (1).


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/jo00829a082DOIArticle
http://pubs.acs.org/doi/abs/10.1021/jo00829a082PublisherArticle
Additional Information:© 1970 American Chemical Society. Received September 2, 1969. Supported by the National Science Foundation. Harkness Fellow of the Commonwealth Fund of New York, 1966-1968. We are grateful to Mr. J. E. Leininger for assistance with the computing.
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NSFUNSPECIFIED
Commonwealth Fund FellowshipUNSPECIFIED
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Caltech Gates and Crellin Laboratories of Chemistry3919
Issue or Number:4
Record Number:CaltechAUTHORS:20151013-111509610
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20151013-111509610
Official Citation:Ring inversion of perfluoro-p-dithiane James Edgar. Anderson, Donald Robert. Davis, and John D. Roberts The Journal of Organic Chemistry 1970 35 (4), 1195-1196 DOI: 10.1021/jo00829a082
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61044
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:15 Oct 2015 03:28
Last Modified:03 Oct 2019 09:03

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