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Nuclear Magnetic Resonance Spectroscopy. Proton Spectra of Diallylmercury

Zieger, Herman E. and Roberts, John D. (1969) Nuclear Magnetic Resonance Spectroscopy. Proton Spectra of Diallylmercury. Journal of Organic Chemistry, 34 (10). pp. 2826-2828. ISSN 0022-3263. https://resolver.caltech.edu/CaltechAUTHORS:20151013-145411658

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Abstract

Changes have been observed in the nmr spectra of diallylmercury as a function of temperature which seem explicable in terms of allylic rearrangement and intermolecular exchange. Analysis of the proton spectra of diallylmercury spectra using a modified LAOCOON II computer program gave coupling constant and chemical shift parameters which reproduced the spectra at 60, 100, and 220 MHz.


Item Type:Article
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http://dx.doi.org/10.1021/jo01262a006DOIArticle
http://pubs.acs.org/doi/abs/10.1021/jo01262a006PublisherArticle
Additional Information:© 1969 American Chemical Society. Received March 6, 1969. Supported in part by the National Science Foundation. We thank Professor S. I. Chan for assistance in securing 100-MHz spectra and for valuable suggestions. Mr. J. H. Prestegard obtained the 220-MHz spectrum and carried out the spin decoupling experiment.
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Issue or Number:10
Record Number:CaltechAUTHORS:20151013-145411658
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20151013-145411658
Official Citation:Nuclear magnetic resonance spectroscopy. Proton spectra of diallylmercury Herman E. Zieger and John D. Roberts The Journal of Organic Chemistry 1969 34 (10), 2826-2828 DOI: 10.1021/jo01262a006
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61071
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:14 Oct 2015 19:38
Last Modified:03 Oct 2019 09:04

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