Hagen, R. and Roberts, John D. (1969) Nuclear Magnetic Resonance Spectroscopy. ^(13)C Spectra of Aliphatic Carboxylic Acids and Carboxylate Anions. Journal of the American Chemical Society, 91 (16). pp. 4504-4506. ISSN 0002-7863. doi:10.1021/ja01044a032. https://resolver.caltech.edu/CaltechAUTHORS:20151013-145412485
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Abstract
The ^(13)C chemical shifts of each of the carbons of the simple aliphatic carboxylic acids and their corresponding anions from formic to valeric acid have been measured in aqueous solution. Perhaps surprisingly, ionization of an aliphatic acid results in a downfield shift of its carbon resonances. The results have been correlated with other substituent effects, with ^(13)C and H resonances in corresponding hydrocarbons, and with the distance between the carboxylic(ate) group and the carbons undergoing resonance absorption.
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| Additional Information: | © 1969 American Chemical Society. Received January 10, 1969. Supported by Public Health Service Research Grant 11070-04 from the Division of General Medical Sciences. | |||||||||
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| Issue or Number: | 16 | |||||||||
| DOI: | 10.1021/ja01044a032 | |||||||||
| Record Number: | CaltechAUTHORS:20151013-145412485 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151013-145412485 | |||||||||
| Official Citation: | Nuclear magnetic resonance spectroscopy. Carbon-13 spectra of aliphatic carboxylic acids and carboxylate anions R. Hagen and John D. Roberts Journal of the American Chemical Society 1969 91 (16), 4504-4506 DOI: 10.1021/ja01044a032 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 61073 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 14 Oct 2015 21:50 | |||||||||
| Last Modified: | 10 Nov 2021 22:44 |
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