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Nuclear Magnetic Resonance Spectroscopy. Low-Temperature Studies of Diallylmagnesium

Zieger, Herman E. and Roberts, John D. (1969) Nuclear Magnetic Resonance Spectroscopy. Low-Temperature Studies of Diallylmagnesium. Journal of Organic Chemistry, 34 (6). pp. 1976-1977. ISSN 0022-3263. https://resolver.caltech.edu/CaltechAUTHORS:20151013-145413050

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Abstract

Allylic organoalkali metal compounds have been observed to exhibit reversible changes in nmr spectra (e.g., AA'BB'C → AB_4 for allyllithium) over the temperature range from -100 to + 110º. In contrast, allymagnesium bromide is reported to display a simple AB_4 spectrum at -80º and diallylmagnesiurn to behave similarly from -60 to +37º in tetrahydrofuran.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/jo01258a104DOIArticle
http://pubs.acs.org/doi/abs/10.1021/jo01258a104PublisherArticle
Additional Information:© 1969 American Chemical Society. Received July 9, 1968. Supported in part by the National Science Foundation.
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Funding AgencyGrant Number
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Other Numbering System NameOther Numbering System ID
Caltech Gates and Crellin Laboratories of Chemistry3706
Issue or Number:6
Record Number:CaltechAUTHORS:20151013-145413050
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20151013-145413050
Official Citation:Nuclear magnetic resonance spectroscopy. Low temperature studies of diallylmagnesium Herman E. Zieger and John D. Roberts The Journal of Organic Chemistry 1969 34 (6), 1976-1977 DOI: 10.1021/jo01258a104
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61075
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:14 Oct 2015 19:26
Last Modified:03 Oct 2019 09:04

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