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Carbon-13 and Nitrogen-15 Nuclear Magnetic Resonance Spectroscopy of Some (η^5-Cyclopentadienyl)nitrosyl Complexes of the Group 6B Elements

Botto, Robert E. and Kolthammer, Brian W. S. and Legzdins, Peter and Roberts, John D. (1979) Carbon-13 and Nitrogen-15 Nuclear Magnetic Resonance Spectroscopy of Some (η^5-Cyclopentadienyl)nitrosyl Complexes of the Group 6B Elements. Inorganic Chemistry, 18 (7). pp. 2049-2051. ISSN 0020-1669. http://resolver.caltech.edu/CaltechAUTHORS:20151013-145413632

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Abstract

During the past few years there have been considerable advances in the detection of nitrogen-15 NMR signals at the natural-abundance level. Consequently, it is reasonable to expect that ^(15)N NMR spectra can be obtained for transition-metal nitrosyl complexes. Furthermore, these spectra should provide detailed structural and electronic information about the nitrosyl species in much the same way that ^(13)C NMR spectra elucidate the properties of transition-metal carbonyl compound. We now report the results of the first ^(15)N NMR study of some organometallic nitrosyl complexes, namely, η^5-cyclopentadienyl)nitrosyl derivatives of chromium, molybdenum, and tungsten, and we also compare the ^(15)N and ^(13)C chemical shifts exhibited by these compounds.


Item Type:Article
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http://dx.doi.org/10.1021/ic50197a073DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ic50197a073PublisherArticle
Additional Information:© 1979 American Chemical Society. Received February 20, 1979. Supported by the National Science Foundation and by the National Research Council of Canada.
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National Research Council of CanadaUNSPECIFIED
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Caltech Gates and Crellin Laboratories of Chemistry5979
Record Number:CaltechAUTHORS:20151013-145413632
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20151013-145413632
Official Citation:Carbon-13 and nitrogen-15 nuclear magnetic resonance spectroscopy of some (.eta.5-cyclopentadienyl)nitrosyl complexes of the Group 6B elements Robert E. Botto, Brian W. S. Kolthammer, Peter Legzdins, and John D. Roberts Inorganic Chemistry 1979 18 (7), 2049-2051 DOI: 10.1021/ic50197a073
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61077
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:14 Oct 2015 21:44
Last Modified:14 Oct 2015 21:44

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