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Nuclear Magnetic Resonance Spectroscopy. A Reinvestigation of the Kinetic Parameters for Inversion of 1,2,2-Trimethylaziridine

Jautelat, Manfred and Roberts, John D. (1969) Nuclear Magnetic Resonance Spectroscopy. A Reinvestigation of the Kinetic Parameters for Inversion of 1,2,2-Trimethylaziridine. Journal of the American Chemical Society, 91 (3). pp. 642-645. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20151013-145414513

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Abstract

Kinetic parameters for inversion of 1,2,2-trimethylaziridine have been evaluated by the line-shape method for the temperature-dependent nmr spectra of the neat liquid and solutions in acetone, benzene, and chloroform. The previously reported activation energy for inversion of this substance is substantially too low. There appears to be a striking difference in activation energy, but not in rate, for inversion in acetone and in chloroform.


Item Type:Article
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http://dx.doi.org/10.1021/ja01031a021DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja01031a021PublisherArticle
Additional Information:© 1969 American Chemical Society. Received May 13, 1968. Supported by the National Science Foundation.
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Caltech Gates and Crellin Laboratories of Chemistry3674
Issue or Number:3
Record Number:CaltechAUTHORS:20151013-145414513
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20151013-145414513
Official Citation:Nuclear magnetic resonance spectroscopy. Reinvestigation of the kinetic parameters for inversion of 1,2,2-trimethylaziridine Manfred Jautelat and John D. Roberts Journal of the American Chemical Society 1969 91 (3), 642-645 DOI: 10.1021/ja01031a021
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61080
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:14 Oct 2015 19:28
Last Modified:03 Oct 2019 09:04

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