CaltechAUTHORS
Published March 1, 1968 | Version public
Journal Article Metadata-only

Nuclear Magnetic Resonance Spectroscopy. Carbon-13 Coupling Constants in Organometallic Compounds

Creators

Abstract

High-resolution, natural-abundance ^(13)C nuclear magnetic resonance spectra have been obtained for the tetramethyl derivatives of group IV and the dimethyl derivatives of group IIb. The one-bond coupling constants between carbon and the spin 1/2 metal atoms as well as the "through-metal" vicinal carbon-proton coupling constants are discussed in terms of the Fermi contact coupling mechanism.

Additional Information

© 1968 American Chemical Society. Received October 4, 1967. Supported in part by the National Science Foundation and the Public Health Service Research Grant 11072-04 from the Division of General Medical Sciences. National Science Foundation Predoctoral Fellow, 1965-1967.

Additional details

Identifiers

Eprint ID
61110
Resolver ID
CaltechAUTHORS:20151014-144940143

Funding

NSF
U.S. Public Health Service (USPHS)
11072-04
NSF Predoctoral Fellowship

Dates

Created
2015-10-15
Created from EPrint's datestamp field
Updated
2021-11-10
Created from EPrint's last_modified field

Caltech Custom Metadata

Other Numbering System Name
Caltech Gates and Crellin Laboratories of Chemistry
Other Numbering System Identifier
3560