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Nuclear Magnetic Resonance Spectroscopy. Carbon-13 Coupling Constants in Organometallic Compounds

Weigert, Frank J. and Winokur, Melvin and Roberts, John D. (1968) Nuclear Magnetic Resonance Spectroscopy. Carbon-13 Coupling Constants in Organometallic Compounds. Journal of the American Chemical Society, 90 (6). pp. 1566-1569. ISSN 0002-7863. doi:10.1021/ja01008a030.

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High-resolution, natural-abundance ^(13)C nuclear magnetic resonance spectra have been obtained for the tetramethyl derivatives of group IV and the dimethyl derivatives of group IIb. The one-bond coupling constants between carbon and the spin 1/2 metal atoms as well as the "through-metal" vicinal carbon-proton coupling constants are discussed in terms of the Fermi contact coupling mechanism.

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Additional Information:© 1968 American Chemical Society. Received October 4, 1967. Supported in part by the National Science Foundation and the Public Health Service Research Grant 11072-04 from the Division of General Medical Sciences. National Science Foundation Predoctoral Fellow, 1965-1967.
Funding AgencyGrant Number
U.S. Public Health Service (USPHS)11072-04
NSF Predoctoral FellowshipUNSPECIFIED
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Caltech Gates and Crellin Laboratories of Chemistry3560
Issue or Number:6
Record Number:CaltechAUTHORS:20151014-144940143
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Official Citation:Nuclear magnetic resonance spectroscopy. Carbon-13 coupling constants in organometallic compounds Frank J. Weigert, Melvin Winokur, and John D. Roberts Journal of the American Chemical Society 1968 90 (6), 1566-1569 DOI: 10.1021/ja01008a030
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61110
Deposited By: Ruth Sustaita
Deposited On:15 Oct 2015 17:28
Last Modified:10 Nov 2021 22:44

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