Weigert, Frank J. and Winokur, Melvin and Roberts, John D. (1968) Nuclear Magnetic Resonance Spectroscopy. Carbon-13 Coupling Constants in Organometallic Compounds. Journal of the American Chemical Society, 90 (6). pp. 1566-1569. ISSN 0002-7863. doi:10.1021/ja01008a030. https://resolver.caltech.edu/CaltechAUTHORS:20151014-144940143
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Abstract
High-resolution, natural-abundance ^(13)C nuclear magnetic resonance spectra have been obtained for the tetramethyl derivatives of group IV and the dimethyl derivatives of group IIb. The one-bond coupling constants between carbon and the spin 1/2 metal atoms as well as the "through-metal" vicinal carbon-proton coupling constants are discussed in terms of the Fermi contact coupling mechanism.
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Additional Information: | © 1968 American Chemical Society. Received October 4, 1967. Supported in part by the National Science Foundation and the Public Health Service Research Grant 11072-04 from the Division of General Medical Sciences. National Science Foundation Predoctoral Fellow, 1965-1967. | |||||||||
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Issue or Number: | 6 | |||||||||
DOI: | 10.1021/ja01008a030 | |||||||||
Record Number: | CaltechAUTHORS:20151014-144940143 | |||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151014-144940143 | |||||||||
Official Citation: | Nuclear magnetic resonance spectroscopy. Carbon-13 coupling constants in organometallic compounds Frank J. Weigert, Melvin Winokur, and John D. Roberts Journal of the American Chemical Society 1968 90 (6), 1566-1569 DOI: 10.1021/ja01008a030 | |||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
ID Code: | 61110 | |||||||||
Collection: | CaltechAUTHORS | |||||||||
Deposited By: | Ruth Sustaita | |||||||||
Deposited On: | 15 Oct 2015 17:28 | |||||||||
Last Modified: | 10 Nov 2021 22:44 |
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