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Efforts toward the Synthesis of Aliphatic Iodonium Salts

Dence, Joseph B. and Roberts, John D. (1968) Efforts toward the Synthesis of Aliphatic Iodonium Salts. Journal of Organic Chemistry, 33 (3). pp. 1251-1253. ISSN 0022-3263. doi:10.1021/jo01267a073.

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Although diaryliodonium salts have been known for almost 74 years salts in which one or both of the ligands are not aromatic are quite rare. Some years ago, Lachman tried unsuccessfully to prepare phenylethyliodonium chloride from diethylzinc and iodobenzene dichloride. Neilands and coworkers have prepared some interesting iodonium betaines derived from the enolate anions of dimedone, methyl acetoacetate, 5-phenyl-1 ,3-cyclohexanedione, and dibenzoylmethane. Recently, Beringer and Galton have synthesized some acetylenic iodonium salts by the reaction between a lithium acetylide and iodobenzene dichloride.

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Additional Information:© 1968 American Chemical Society. Received September 5, 1967. Supported by the National Science Foundation.
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Caltech Gates and Crellin Laboratory of Chemistry3565
Issue or Number:3
Record Number:CaltechAUTHORS:20151014-144940420
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Official Citation:Efforts toward the synthesis of liphatic iodonium salts Joseph B. Dence and John D. Roberts The Journal of Organic Chemistry 1968 33 (3), 1251-1253 DOI: 10.1021/jo01267a073
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61111
Deposited By: Ruth Sustaita
Deposited On:15 Oct 2015 20:15
Last Modified:10 Nov 2021 22:44

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