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A Reinterpretation of the Nuclear Magnetic Resonance Spectrum of Cyclobutene

Hill, E. Alexander and Roberts, John D. (1967) A Reinterpretation of the Nuclear Magnetic Resonance Spectrum of Cyclobutene. Journal of the American Chemical Society, 89 (9). pp. 2047-2049. ISSN 0002-7863. http://resolver.caltech.edu/CaltechAUTHORS:20151014-144941522

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Abstract

A reinvestigation of the nmr spectrum of cyclobutene has led to a revised set of coupling constants which is consistent both with the ^(13)C proton satellite spectra of cyclobutene and with the spectra of partially deuterated cyclobutene isomers. The present treatment differs from that reported previously by inclusion of long-range ^(13)C-C-H and ^(13)C-C-C-H couplings which in effect make the two methylene groups and the two vinyl hydrogens nonequivalent.


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http://dx.doi.org/10.1021/ja00985a013DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja00985a013PublisherArticle
Additional Information:© 1967 American Chemical Society. Received December 9, 1966. Grateful acknowledgment is made to the donors of the Petroleum Research Fund administered by the American Chemical Society for partial support of this research. California Institute of Technology; research supported in part by the National Science Foundation.
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American Chemical Society Petroleum Research FundUNSPECIFIED
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Caltech Gates and Crellin Laboratories of Chemistry3446
Record Number:CaltechAUTHORS:20151014-144941522
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20151014-144941522
Official Citation:A Reinterpretation of the Nuclear Magnetic Resonance Spectrum of Cyclobutene E. Alexander Hill and John D. Roberts Journal of the American Chemical Society 1967 89 (9), 2047-2049 DOI: 10.1021/ja00985a013
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61115
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:15 Oct 2015 17:25
Last Modified:15 Oct 2015 17:25

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