Clark, David T. and Roberts, John D. (1966) Nitrogen-15 Magnetic Resonance Spectroscopy. VII. Chemical Shifts of para-Substituted Nitrobenzenes. Journal of the American Chemical Society, 88 (4). pp. 745-747. ISSN 0002-7863. doi:10.1021/ja00956a025. https://resolver.caltech.edu/CaltechAUTHORS:20151014-144944278
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Abstract
The ^(15)N chemical shifts of a series of para-substituted nitrobenzenes have been measured. Comparison with the para-^(13)C chemical shifts in monosubstituted benzenes and with ^(19)F chemical shifts in para-substituted fluorobenzenes, indicates that similar factors determine the chemical shifts of these three nuclei. With p-nitroaniline, the ^(15)N chemical shift appears to have an extra paramagnetic contribution, since this is the only compound studied that does not fit the correlation with ^(13)C and ^(19)F chemical shifts.
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| Additional Information: | © 1966 American Chemical Society. Received September 30, 1965. Supported in part by the Public Health Service Research Grant 11072-02 from the Division of General Medical Sciences and the National Science Foundation. | |||||||||
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| Issue or Number: | 4 | |||||||||
| DOI: | 10.1021/ja00956a025 | |||||||||
| Record Number: | CaltechAUTHORS:20151014-144944278 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151014-144944278 | |||||||||
| Official Citation: | Nitrogen-15 Magnetic Resonance Spectroscopy. VII. Chemical Shifts of para-Substituted Nitrobenzenes David T. Clark and John D. Roberts Journal of the American Chemical Society 1966 88 (4), 745-747 DOI: 10.1021/ja00956a025 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 61125 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 15 Oct 2015 20:05 | |||||||||
| Last Modified: | 10 Nov 2021 22:44 |
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