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Mechanism of the Diels-Alder Reaction. The Question of the “Internal” Pathway for the Thermal endo-exo Isomerizations of the 5-Norbornene-2,3-dicarboxylic Anhydrides

Ganter, Camille and Scheidegger, Ulrich and Roberts, John D. (1965) Mechanism of the Diels-Alder Reaction. The Question of the “Internal” Pathway for the Thermal endo-exo Isomerizations of the 5-Norbornene-2,3-dicarboxylic Anhydrides. Journal of the American Chemical Society, 87 (12). pp. 2771-2772. ISSN 0002-7863. http://resolver.caltech.edu/CaltechAUTHORS:20151015-104906727

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Abstract

Much information bearing on the mechanism of the Diels-Alder reaction has been obtained from studies of isomerizations of various adducts of cyclopentadiene. One of the most interesting and important of these isomerizations is the conversion of the endocyclopentadiene-maleic anhydride adduct [5-norbornene-2,3-endo-dicarboxylic anhydride (N)12] to the corresponding exo isomer (X) at 190º.


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http://dx.doi.org/10.1021/ja01090a053DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja01090a053PublisherArticle
Additional Information:© 1965 American Chemical Society. Received April 28, 1965. Supported in part by the National Science Foundation.
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Caltech Gates and Crellin Laboratories of Chemistry3222
Record Number:CaltechAUTHORS:20151015-104906727
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20151015-104906727
Official Citation:Mechanism of the Diels-Alder Reaction. The Question of the “Internal” Pathway for the Thermal endo-exo Isomerizations of the 5-Norbornene-2,3-dicarboxylic Anhydrides Camille Ganter, Ulrich Scheidegger, and John D. Roberts Journal of the American Chemical Society 1965 87 (12), 2771-2772 DOI: 10.1021/ja01090a053
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ID Code:61157
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:15 Oct 2015 21:32
Last Modified:15 Oct 2015 21:32

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