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Magnetic Resonance Spectroscopy. The Configurational Stability of Primary Grignard Reagents. 3,3-Dimethylbutylmagnesium Chloride

Whitesides, George M. and Witanowski, Michal and Roberts, John D. (1965) Magnetic Resonance Spectroscopy. The Configurational Stability of Primary Grignard Reagents. 3,3-Dimethylbutylmagnesium Chloride. Journal of the American Chemical Society, 87 (13). pp. 2854-2862. ISSN 0002-7863. http://resolver.caltech.edu/CaltechAUTHORS:20151015-104907132

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Abstract

Detailed examination of the temperature dependence of the n.m.r. spectra of 3,3-dimethylbutylmagnesium chloride and bis(3,3-dimethylbutyl)magnesium indicates that inversion of configuration at the -CH_2Mg center occurs rapidly in ether solution at room temperature.


Item Type:Article
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http://dx.doi.org/10.1021/ja01091a014DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja01091a014PublisherArticle
Additional Information:© 1965 American Chemical Society. Received January 9, 1965. Supported in part by the Office of Naval Research and the National Science Foundation. Presented at the 10th Reaction Mechanisms Conference, Corvallis, Ore., June 24, 1964.
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Office of Naval Research (ONR)UNSPECIFIED
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Caltech Gates and Crellin Laboratories of Chemistry3186
Record Number:CaltechAUTHORS:20151015-104907132
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20151015-104907132
Official Citation:Magnetic Resonance Spectroscopy. The Configurational Stability of Primary Grignard Reagents. 3,3-Dimethylbutylmagnesium Chloride George M. Whitesides, Michal Witanowski, and John D. Roberts Journal of the American Chemical Society 1965 87 (13), 2854-2862 DOI: 10.1021/ja01091a014
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ID Code:61158
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:15 Oct 2015 21:46
Last Modified:15 Oct 2015 21:46

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