CaltechAUTHORS
  A Caltech Library Service

Nitrogen-15 Magnetic Resonance Spectroscopy. VI. Pyrimidine Derivatives

Roberts, Bryan W. and Lambert, Joseph B. and Roberts, John D. (1965) Nitrogen-15 Magnetic Resonance Spectroscopy. VI. Pyrimidine Derivatives. Journal of the American Chemical Society, 87 (23). pp. 5439-5441. ISSN 0002-7863. http://resolver.caltech.edu/CaltechAUTHORS:20151015-104928205

Full text is not posted in this repository. Consult Related URLs below.

Use this Persistent URL to link to this item: http://resolver.caltech.edu/CaltechAUTHORS:20151015-104928205

Abstract

Proton and nitrogen-15 magnetic resonance spectra of several derivatives of pyrimidine have been studied. Long-range ^(15)N-H couplings were observed in uracil- ^(15)N_2, 2,4-dichloropyrimidine-^(15)N_2, 2,4-dimethoxypyrimidine- ^(15)N_2, 1-methyl-4-methoxy-2-pyrimidone ^(15)-N_2, and 1-methylcytosine-^(15)N_2. A particularly large ^(15)N_(1)-C-H coupling (12.5 c.p.s.) has been observed in 2,4-dichloropyrimidine-^(15)N_2. 1-Methylcytosine-^(15)N_2 has been shown to protonate at N_(3) in agreement with previously reported work on 1-methylcytosine labeled only in the amino group.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja00951a033DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja00951a033PublisherArticle
Additional Information:© 1965 American Chemical Society. Received July 30, 1965. Supported in part by the Air Force Office of Scientific Research, the Public Health Service Research Grant 11072-02 from the Division of General Medical Sciences, and the National Science Foundation. National Academy of Sciences-National Research Council Postdoctoral Fellow, 1963-1964. National Science Foundation Predoctoral Fellow, 1962-1965.
Funders:
Funding AgencyGrant Number
Air Force Office of Scientific Research (AFOSR)UNSPECIFIED
U.S. Public Health Service (USPHS)11072-02
NSFUNSPECIFIED
National Academy of Sciences-National Research Council Postdoctoral FellowshipUNSPECIFIED
NSF Predoctoral FellowshipUNSPECIFIED
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Caltech Gates and Crellin Laboratories of Chemistry3247
Record Number:CaltechAUTHORS:20151015-104928205
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20151015-104928205
Official Citation:Nitrogen-15 Magnetic Resonance Spectroscopy. VI. Pyrimidine Derivatives Bryan W. Roberts, Joseph B. Lambert, and John D. Roberts Journal of the American Chemical Society 1965 87 (23), 5439-5441 DOI: 10.1021/ja00951a033
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61163
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:16 Oct 2015 17:46
Last Modified:16 Oct 2015 17:46

Repository Staff Only: item control page