Nagarajan, Kuppuswamy and Caserio, Marjorie C. and Roberts, John D. (1964) Small-Ring Compounds. XXXX. The Structure and Properties of a Dimer of Triphenylfluorocyclobutadiene. Journal of the American Chemical Society, 86 (3). pp. 449-453. ISSN 0002-7863. doi:10.1021/ja01057a032. https://resolver.caltech.edu/CaltechAUTHORS:20151016-112437144
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Abstract
The chemistry of the previously described substance, C_(44)H_(30)F_2 from the reaction of 1,1-difluoro-2,4-dichloro-3-phenylcyclobutene and phenyllithium is described. The physical and chemical data presented are best interpreted in terms of an anti-tricyclo[4.2.0.0] octadiene structure for the substance which could arise by dimerization of triphenylfluorocyclobutadiene. The recent X-ray diffraction study of the substance by Hughes and Fritchie has confirmed the proposed structure.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1964 American Chemical Society. Received August 26, 1963. Supported in part by the National Science Foundation. | |||||||||
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| Issue or Number: | 3 | |||||||||
| DOI: | 10.1021/ja01057a032 | |||||||||
| Record Number: | CaltechAUTHORS:20151016-112437144 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151016-112437144 | |||||||||
| Official Citation: | Small-Ring Compounds. XXXX. The Structure and Properties of a Dimer of Triphenylfluorocyclobutadiene Kuppuswamy. Nagarajan, Marjorie C. Caserio, and John D. Roberts Journal of the American Chemical Society 1964 86 (3), 449-453 DOI: 10.1021/ja01057a032 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 61204 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 16 Oct 2015 21:22 | |||||||||
| Last Modified: | 10 Nov 2021 22:45 |
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