Baldwin, John E. and Roberts, John D. (1963) Mechanism of the Thermal Isomerization of 5-Norbornene-2,3-endo-Dicarboxylic Anhydride. Journal of the American Chemical Society, 85 (1). pp. 115-116. ISSN 0002-7863. doi:10.1021/ja00884a029. https://resolver.caltech.edu/CaltechAUTHORS:20151016-112438623
Full text is not posted in this repository. Consult Related URLs below.
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20151016-112438623
Abstract
The thermal interconversions of α and β-1-hydroxydicyclopentadiene with syn- and anti-8-hydroxydicyclopentadiene, respectively, with retention of optical activity and analogous rearrangements have been considered in mechanistic descriptions of the Diels-Alder reaction. In the case of deuterium-labeled methacrolein dimer, an internal stereospecific pathway for rearrangement and complete dissociation of the dimer are very much in competition at 180°, and both reactions occur simultaneously. As was noted, the possibility that different energy paths are involved in the two processes remained unsettled.
Item Type: | Article | |||||||||
---|---|---|---|---|---|---|---|---|---|---|
Related URLs: |
| |||||||||
Additional Information: | © 1963 American Chemical Society. Received November 15, 1962. Supported in part by the National Science Foundation. | |||||||||
Funders: |
| |||||||||
Other Numbering System: |
| |||||||||
Issue or Number: | 1 | |||||||||
DOI: | 10.1021/ja00884a029 | |||||||||
Record Number: | CaltechAUTHORS:20151016-112438623 | |||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151016-112438623 | |||||||||
Official Citation: | Mechanism of the Thermal Isomerization of 5-Norbornene-2,3-endo-Dicarboxylic Anhydride John E. Baldwin and John D. Roberts Journal of the American Chemical Society 1963 85 (1), 115-116 DOI: 10.1021/ja00884a029 | |||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
ID Code: | 61209 | |||||||||
Collection: | CaltechAUTHORS | |||||||||
Deposited By: | Ruth Sustaita | |||||||||
Deposited On: | 16 Oct 2015 21:35 | |||||||||
Last Modified: | 10 Nov 2021 22:45 |
Repository Staff Only: item control page