Lambert, Joseph B. and Roberts, John D. (1963) Conformational Studies of Cyclobutane Systems. Journal of the American Chemical Society, 85 (22). pp. 3710-3711. ISSN 0002-7863. doi:10.1021/ja00905a048. https://resolver.caltech.edu/CaltechAUTHORS:20151016-112438879
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Abstract
Isolated attempts have been made to detect the presence of nonplanarity in cyclobutane rings. Significant deviations from planarity have been measured for cyclobutane, octafluorocyclobutane, octachlorocyclobutane and bromocyclobutane. The results in the first two cases, however, have not been without controversy. It was the object of the present work to devise a fairly general, but still straightforward, method of detecting the presence and determining the magnitude of puckering in substituted cyclobutane rings, and to ascertain whether the results could be interpreted in terms of an equilibrium between axial (I) and equatorial (II) conformations.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1963 American Chemical Society. Received August 5, 1963. Supported in part by the Office of Naval Research and the National Science Foundation. | |||||||||
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| Issue or Number: | 22 | |||||||||
| DOI: | 10.1021/ja00905a048 | |||||||||
| Record Number: | CaltechAUTHORS:20151016-112438879 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151016-112438879 | |||||||||
| Official Citation: | Conformational Studies of Cyclobutane Systems Joseph B. Lambert and John D. Roberts Journal of the American Chemical Society 1963 85 (22), 3710-3711 DOI: 10.1021/ja00905a048 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 61210 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 16 Oct 2015 21:23 | |||||||||
| Last Modified: | 10 Nov 2021 22:45 |
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