Cowan, Dwaine O. and Hsu, John and Roberts, John D. (1964) Exchange of Magnesium between the Ethyl Grignard Reagent and Magnesium Bromide. Journal of Organic Chemistry, 29 (12). pp. 3688-3690. ISSN 0022-3263. doi:10.1021/jo01035a502. https://resolver.caltech.edu/CaltechAUTHORS:20151016-143423525
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Abstract
Much has been said but little settled about the precise nature of the Grignard reagent. The X-ray structure studies of Stucky and Rundle, the vapor pressure studies of Vreugdenhil and Blomberg, the work of Ashby and Becker and the far-infrared experiments of Salinger and Mosher all indicate that the Grignard reagent can exist, at least in part, as a monomer (RMg-X) under a variety of experimental conditions.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1964 American Chemical Society. Received August 4, 1964. Supported by the National Science Foundation: National Science Foundation Undergraduate Fellow, summer 1963. | |||||||||
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| Issue or Number: | 12 | |||||||||
| DOI: | 10.1021/jo01035a502 | |||||||||
| Record Number: | CaltechAUTHORS:20151016-143423525 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151016-143423525 | |||||||||
| Official Citation: | Exchange of Magnesium between the Ethyl Grignard Reagent and Magnesium Bromide Dwaine O. Cowan, John Hsu, and John D. Roberts The Journal of Organic Chemistry 1964 29 (12), 3688-3690 DOI: 10.1021/jo01035a502 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 61218 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 16 Oct 2015 22:28 | |||||||||
| Last Modified: | 10 Nov 2021 22:45 |
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