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Exchange of Magnesium between the Ethyl Grignard Reagent and Magnesium Bromide

Cowan, Dwaine O. and Hsu, John and Roberts, John D. (1964) Exchange of Magnesium between the Ethyl Grignard Reagent and Magnesium Bromide. Journal of Organic Chemistry, 29 (12). pp. 3688-3690. ISSN 0022-3263. https://resolver.caltech.edu/CaltechAUTHORS:20151016-143423525

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Abstract

Much has been said but little settled about the precise nature of the Grignard reagent. The X-ray structure studies of Stucky and Rundle, the vapor pressure studies of Vreugdenhil and Blomberg, the work of Ashby and Becker and the far-infrared experiments of Salinger and Mosher all indicate that the Grignard reagent can exist, at least in part, as a monomer (RMg-X) under a variety of experimental conditions.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/jo01035a502DOIArticle
http://pubs.acs.org/doi/abs/10.1021/jo01035a502PublisherArticle
Additional Information:© 1964 American Chemical Society. Received August 4, 1964. Supported by the National Science Foundation: National Science Foundation Undergraduate Fellow, summer 1963.
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NSFUNSPECIFIED
NSF Undergraduate FellowshipUNSPECIFIED
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Caltech Gates and Crellin Laboratories of Chemistry3148
Issue or Number:12
Record Number:CaltechAUTHORS:20151016-143423525
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20151016-143423525
Official Citation:Exchange of Magnesium between the Ethyl Grignard Reagent and Magnesium Bromide Dwaine O. Cowan, John Hsu, and John D. Roberts The Journal of Organic Chemistry 1964 29 (12), 3688-3690 DOI: 10.1021/jo01035a502
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61218
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:16 Oct 2015 22:28
Last Modified:03 Oct 2019 09:05

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