Rotationally resolved multiphoton ionization photoelectron spectroscopy of the [a ^1Δ]3dπ^2Φ and [a ^1Δ]5pπ^2Φ Rydberg states of the SH radical

Milan, J. B. and Buma, W. J. and de Lange, C. A. and Wang, Kwanghsi and McKoy, V. (1997) Rotationally resolved multiphoton ionization photoelectron spectroscopy of the [a ^1Δ]3dπ^2Φ and [a ^1Δ]5pπ^2Φ Rydberg states of the SH radical. Journal of Chemical Physics, 107 (8). pp. 2782-2792. ISSN 0021-9606. doi:10.1063/1.474635. https://resolver.caltech.edu/CaltechAUTHORS:20151019-143011167

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Abstract

Experimental and theoretical results on the rotationally resolved photoelectron spectra of the [a ^1Δ]3dπ^2Φ(v'=0) and the [a^ 1Δ]5pπ^2Φ(v'=0) Rydberg states of the SH radical are presented. In particular, for the former state, ionization via a large number of members of different rotational branches is considered. The interplay between experiment and ab initio calculations, including alignment, allows for a detailed interpretation of the results. Asymmetries apparent in the rotational ionic distributions and the observed suppression of transitions involving a large change in angular momentum can be explained on the basis of the theory.

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Article

Related URLs:

URL	URL Type	Description
http://dx.doi.org/10.1063/1.474635	DOI	Article
http://scitation.aip.org/content/aip/journal/jcp/107/8/10.1063/1.474635	Publisher	Article

Alternate Title:

Rotationally resolved multiphoton ionization photoelectron spectroscopy of the [a1Δ]3dπ2Φ and [a1Δ]5pπ2Φ Rydberg states of the SH radical

Additional Information:

© 1997 American Institute of Physics. (Received 7 March 1997; accepted 14 May 1997) The group at the University of Amsterdam gratefully acknowledges the Netherlands Organization for Scientific Research (NWO) for equipment grants and for financial support (J.B.M.). Work at the California Institute of Technology was supported by grants from the Air Force Office of Scientific Research and the Office of Health and Environmental Research of the U.S. Department of Energy. We also acknowledge use of the resources of the Jet Propulsion Laboratory/California Institute of Technology CRAY Y-MP2E/232 supercomputer. Both groups gratefully acknowledge NATO for collaborative Grant No. CRG930183.

Funders:

Funding Agency	Grant Number
Nederlandse Organisatie voor Wetenschappelijk Onderzoek (NWO)	UNSPECIFIED
Air Force Office of Scientific Research (AFOSR)	UNSPECIFIED
Department of Energy (DOE)	UNSPECIFIED
North Atlantic Treaty Organization (NATO)	CRG930183

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DOI:

10.1063/1.474635

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CaltechAUTHORS:20151019-143011167

Persistent URL:

https://resolver.caltech.edu/CaltechAUTHORS:20151019-143011167

Official Citation:

Rotationally resolved multiphoton ionization photoelectron spectroscopy of the [a 1Δ]3dπ 2Φ and [a 1Δ]5pπ 2Φ Rydberg states of the SH radical Milan, J. B. and Buma, W. J. and de Lange, C. A. and Wang, Kwanghsi and McKoy, V., The Journal of Chemical Physics, 107, 2782-2792 (1997), DOI:http://dx.doi.org/10.1063/1.474635

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61263

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CaltechAUTHORS

Deposited By:

George Porter

Deposited On:

27 Oct 2015 16:06

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10 Nov 2021 22:46

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