Rao, R. M. and Poliakoff, E. D. and Wang, Kwanghsi and McKoy, V. (1996) Molecular photoionization as a probe of vibrational–rotational–electronic correlations. Journal of Chemical Physics, 104 (23). pp. 9654-9657. ISSN 0021-9606. doi:10.1063/1.471672. https://resolver.caltech.edu/CaltechAUTHORS:20151019-143012973
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Abstract
We determine the rotationally state‐resolved 2σ_u^(−1) photoionization of N_2 into alternative vibrational channels as a function of energy over a 200 eV range. Experiment and theory reveal that Cooper minima highlight the coupling between electronic, vibrational, and rotational degrees of freedom over this very wide range.
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| Additional Information: | © 1996 American Institute of Physics. (Received 18 March 1996; accepted 12 April 1996) We thank the CAMD staff for their assistance. E. D. P. acknowledges support from NSF (CHE-9315857). Work at Caltech was supported by the Air Force Office of Scientific Research, the Office of Health and Environmental Research of the U.S. Department of Energy, and the JPL/Caltech CRAY Y-MP2E/232 Supercomputer. | |||||||||
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| Issue or Number: | 23 | |||||||||
| DOI: | 10.1063/1.471672 | |||||||||
| Record Number: | CaltechAUTHORS:20151019-143012973 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151019-143012973 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 61267 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | George Porter | |||||||||
| Deposited On: | 20 Oct 2015 21:57 | |||||||||
| Last Modified: | 10 Nov 2021 22:46 |
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