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Molecular photoionization as a probe of vibrational–rotational–electronic correlations

Rao, R. M. and Poliakoff, E. D. and Wang, Kwanghsi and McKoy, V. (1996) Molecular photoionization as a probe of vibrational–rotational–electronic correlations. Journal of Chemical Physics, 104 (23). pp. 9654-9657. ISSN 0021-9606. doi:10.1063/1.471672.

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We determine the rotationally state‐resolved 2σ_u^(−1) photoionization of N_2 into alternative vibrational channels as a function of energy over a 200 eV range. Experiment and theory reveal that Cooper minima highlight the coupling between electronic, vibrational, and rotational degrees of freedom over this very wide range.

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Additional Information:© 1996 American Institute of Physics. (Received 18 March 1996; accepted 12 April 1996) We thank the CAMD staff for their assistance. E. D. P. acknowledges support from NSF (CHE-9315857). Work at Caltech was supported by the Air Force Office of Scientific Research, the Office of Health and Environmental Research of the U.S. Department of Energy, and the JPL/Caltech CRAY Y-MP2E/232 Supercomputer.
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Air Force Office of Scientific Research (AFOSR)UNSPECIFIED
Department of Energy (DOE)UNSPECIFIED
Issue or Number:23
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61267
Deposited By: George Porter
Deposited On:20 Oct 2015 21:57
Last Modified:10 Nov 2021 22:46

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