Rotationally resolved photoelectron spectroscopy of the [a ^1Δ]3dπ ^2Φ Rydberg state of the SH radical

Milan, J. B. and Buma, W. J. and de Lange, C. A. and Wang, Kwanghsi and McKoy, V. (1995) Rotationally resolved photoelectron spectroscopy of the [a ^1Δ]3dπ ^2Φ Rydberg state of the SH radical. Journal of Chemical Physics, 103 (8). pp. 3262-3264. ISSN 0021-9606. doi:10.1063/1.470258. https://resolver.caltech.edu/CaltechAUTHORS:20151019-143013528

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Abstract

Results of calculated and measuredphotoelectron spectra via the [a ^1Δ]3dπ ^2Φ state of SH are reported. These spectra show a strong asymmetry away from classical expectations and only transitions up to ΔN=±2 are observed, in contrast to ΔN=±4 expected for photoionization of a 3dπ orbital. Agreement between the calculated and measured spectra is excellent.

Item Type:

Article

Related URLs:

URL	URL Type	Description
http://dx.doi.org/10.1063/1.470258	DOI	Article
http://scitation.aip.org/content/aip/journal/jcp/103/8/10.1063/1.470258	Publisher	Article

Additional Information:

© 1995 American Institute of Physics. (Received 2 May 1995; accepted 12 June 1995) The group at the University of Amsterdam gratefully acknowledges the Netherlands Organization for Scientific Research (NWO) for equipment grants and for financial support (J.B.M.). Work at the California Institute of Technology was supported by grants from the Air Force Office of Scientific Research and the Office of Health and Environmental Research of the U.S. Department of Energy. We also acknowledge use of the resources of the Jet Propulsion Laboratory/California Institute of Technology CRAY Y-MP2E/232 supercomputer. Both groups gratefully acknowledge NATO for collaborative Grant Number CRG930183.

Funders:

Funding Agency	Grant Number
Nederlandse Organisatie voor Wetenschappelijk Onderzoek (NWO)	UNSPECIFIED
Air Force Office of Scientific Research (AFOSR)	UNSPECIFIED
Department of Energy (DOE)	UNSPECIFIED
North Atlantic Treaty Organization (NATO)	CRG930183

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DOI:

10.1063/1.470258

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CaltechAUTHORS:20151019-143013528

Persistent URL:

https://resolver.caltech.edu/CaltechAUTHORS:20151019-143013528

Official Citation:

Rotationally resolved photoelectron spectroscopy of the [a 1Δ]3dπ 2Φ Rydberg state of the SH radical Milan, J. B. and Buma, W. J. and de Lange, C. A. and Wang, Kwanghsi and McKoy, V., The Journal of Chemical Physics, 103, 3262-3264 (1995), DOI:http://dx.doi.org/10.1063/1.470258

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61269

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CaltechAUTHORS

Deposited By:

George Porter

Deposited On:

20 Oct 2015 22:55

Last Modified:

10 Nov 2021 22:46

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