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Threshold Photoelectron Spectroscopy of the A ^2Π state of CO^+

Wang, Kwanghsi and McKoy, V. (1995) Threshold Photoelectron Spectroscopy of the A ^2Π state of CO^+. Journal of Physical Chemistry, 99 (6). pp. 1643-1648. ISSN 0022-3654. doi:10.1021/j100006a004.

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Results of calculations of single-photon pulsed-field ionization of the 1π orbital of the X ^1Σ^+ (v" = 0) ground state of CO leading to the A Π (v+ = 0-2) excited ionic state are reported. Agreement between the calculated and measured spectra is reasonable except for the A ^2Π_(1/2) (v^+ = 0) level which shows strong autoionization at larger positive ΔJ transitions. Our studies show that the direct photoionization of the In orbital is very atomiclike.

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Additional Information:© 1995 American Chemical Society. Received: August 15, 1994; In Final Form: October 31, 1994. Work at the California Institute of Technology was supported by grants from the Air Force Office of Scientific Research and the Office of Health and Environmental Research of the U.S. Department of Energy. We also acknowledge use of the resources of the Jet Propulsion Laboratory/California Institute of Technology CRAY Y-MP2E/232 supercomputer.
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Air Force Office of Scientific Research (AFOSR)UNSPECIFIED
Department of Energy (DOE)UNSPECIFIED
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Caltech Arthur Amos Noyes Laboratory of Chemical Physics8972
Issue or Number:6
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Official Citation:Threshold Photoelectron Spectroscopy of the A 2.PI. state of CO+ Kwanghsi Wang and V. McKoy The Journal of Physical Chemistry 1995 99 (6), 1643-1648 DOI: 10.1021/j100006a004
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61272
Deposited By: George Porter
Deposited On:20 Oct 2015 21:50
Last Modified:10 Nov 2021 22:46

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