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Ion Distributions for Resonance-Enhanced Multiphoton Ionization of ClO

Wang, Kwanghsi and McKoy, V. (1995) Ion Distributions for Resonance-Enhanced Multiphoton Ionization of ClO. Journal of Physical Chemistry, 99 (6). pp. 1727-1732. ISSN 0022-3654. doi:10.1021/j100006a014.

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Results of theoretical studies of rotationally resolved photoelectron spectra for (2 + 1’) resonance enhanced multiphoton ionization (REMPI) of the C ^2Σ^-, D ^2Σ^-, E ^2Σ^-, and F ^2Σ^- Rydberg states of ClO are presented. Cooper minima are predicted to occur in the electronic continua for photoionization of the D and F states and lead to unusual behavior in the ion rotational distributions. Strong partial wave I mixing is also predicted in the continua for the C and E states due to the nonspherical molecular ion potentials. These Cooper minima and l mixing make the associated photoionization dynamics quite nonatomiclike.

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Additional Information:© 1995 American Chemical Society. Received: August 15, 1994. This work was supported by grants from the National Science Foundation, Air Force Office of Scientific Research, and the Office of Health and Environmental Research of the U.S. Department of Energy. We also acknowledge use of the resources of the Jet Propulsion Laboratory/California Institute of Technology CRAY Y-MP2E/232 Supercomputer.
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Air Force Office of Scientific Research (AFOSR)UNSPECIFIED
Department of Energy (DOE)UNSPECIFIED
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Caltech Arthur Amos Noyes Laboratory of Chemical Physics8971
Issue or Number:6
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Official Citation:Ion Distributions for Resonance-Enhanced Multiphoton Ionization of ClO Kwanghsi Wang and V. McKoy The Journal of Physical Chemistry 1995 99 (6), 1727-1732 DOI: 10.1021/j100006a014
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61274
Deposited By: George Porter
Deposited On:20 Oct 2015 18:51
Last Modified:10 Nov 2021 22:46

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