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Energy dependence of photoion rotational distributions of N_2 and CO

Choi, Heung Cheun and Rao, R. M. and Mihill, A. G. and Kakar, Sandeep and Poliakoff, E. D. and Wang, Kwanghsi and McKoy, V. (1994) Energy dependence of photoion rotational distributions of N_2 and CO. Physical Review Letters, 72 (1). pp. 44-47. ISSN 0031-9007. https://resolver.caltech.edu/CaltechAUTHORS:20151019-143017830

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Abstract

We present the first measurements of rotational distributions for photoionization over extended energy ranges [0 ≤ E_k ≤ 200 eV for N_2 (2σ^(-1)_u) and of 3 ≤ E_k ≤ 125 eV for CO (4σ^(−1))]. The N_2 and CO results show a strikingly unusual and different energy dependence. Although differences are expected due to the absence of a center of symmetry in CO, detailed calculations reveal that this behavior arises from the presence of Cooper minima in the photoelectron continuum (kσ_g) in the case of N_2 and from an f-wave shape resonance for 4σ^(−1) photoionization in CO.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1103/PhysRevLett.72.44DOIArticle
http://journals.aps.org/prl/abstract/10.1103/PhysRevLett.72.44PublisherArticle
Alternate Title:Energy dependence of photoion rotational distributions of N2 and CO
Additional Information:© 1994 American Physical Society. (Received 2 September 1993) The efforts of the CAMD staff are greatly appreciated, and we are particularly indebted to Dr. Volker Saile, Dr. John Scott, and Dr. Eizi Morikawa for their support with the plane grating monochromator. We also acknowledge support from NSF (CHE-9315857) and the Louisiana LEQSF program. Work at California Institute of Technology was supported by grants from the Air Force Office of Scientific Research and the Office of Health and Environmental Research of the U.S. Department of Energy. We also acknowledge the use of resources of the Jet Propulsion Laboratory/California Institute of Technology CRAY Y-MP2E/232 supercomputer.
Funders:
Funding AgencyGrant Number
NSFCHE-9315857
Louisiana LEQSF programUNSPECIFIED
Air Force Office of Scientific Research (AFOSR)UNSPECIFIED
Department of Energy (DOE)UNSPECIFIED
Issue or Number:1
Classification Code:PACS numbers: 33.80.Eh, 33.10. Ev, 33.50.Dq
Record Number:CaltechAUTHORS:20151019-143017830
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20151019-143017830
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61280
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:20 Oct 2015 21:03
Last Modified:03 Oct 2019 09:06

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