Snyder, Eugene I. and Altman, L. J. and Roberts, John D. (1962) Nuclear Magnetic Resonance Spectroscopy. Long-Range Spin Couplings in Vinylacetylene. Journal of the American Chemical Society, 84 (10). p. 2004. ISSN 0002-7863. doi:10.1021/ja00869a046. https://resolver.caltech.edu/CaltechAUTHORS:20151020-073601380
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Abstract
The failure of long-range spin coupling to be observed in the high-resolution proton magnetic resonance spectra of vinylacetylene and propargylaldehyde has been cited as evidence against hyperconjugation as a mechanism for long-range coupling in unsaturated compounds. The reasoning involved has been challenged recently by Hoffman and Gronowitz on theoretical grounds.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1962 American Chemical Society. Received January 6, 1962. Supported in part by the Office of Naval Research and the Undergraduate Research Participation Program of the National Science Foundation. | |||||||||
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| Issue or Number: | 10 | |||||||||
| DOI: | 10.1021/ja00869a046 | |||||||||
| Record Number: | CaltechAUTHORS:20151020-073601380 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151020-073601380 | |||||||||
| Official Citation: | Nuclear Magnetic Resonance Spectroscopy. Long-Range Spin Couplings in Vinylacetylene Eugene I. Snyder, L. J. Altman, and John D. Roberts Journal of the American Chemical Society 1962 84 (10), 2004-2004 DOI: 10.1021/ja00869a046 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 61296 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 20 Oct 2015 19:04 | |||||||||
| Last Modified: | 10 Nov 2021 22:46 |
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