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Nuclear Magnetic Resonance Spectroscopy. Long-Range H-F Spin-Spin Coupling in 1,1-Difluoro-2,2-dichloro-3-phenyl-3-methylcyclobutane

Takahashi, Masaaki and Davis, Donald R. and Roberts, John D. (1962) Nuclear Magnetic Resonance Spectroscopy. Long-Range H-F Spin-Spin Coupling in 1,1-Difluoro-2,2-dichloro-3-phenyl-3-methylcyclobutane. Journal of the American Chemical Society, 84 (15). pp. 2935-2938. ISSN 0002-7863. http://resolver.caltech.edu/CaltechAUTHORS:20151020-073602006

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Abstract

A 2 C.P.S. long-range H-F spin-spin coupling has been observed over fire saturated bonds in 1,1-difluoro-2,2-dichloro-3-phenyl-3-metliylcyclobutane, involving one of the fluorines at the 1-position and the protons of the 3-methyl group. Comparison of the spectrum with that of stereospecifically labeled 4-deuterio derivatives suggests that the fluorine involved in the long-range coupling is the one cis to the methyl group.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja00874a018DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja00874a018PublisherArticle
Additional Information:© 1962 American Chemical Society. Received March 7, 1962. Supported in part by the Kureha Chemical Ind. Co. (Japan) and the Office of Naval Research.
Funders:
Funding AgencyGrant Number
Kureha Chemical Ind. Co.UNSPECIFIED
Office of Naval Research (ONR)UNSPECIFIED
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Caltech Gates and Crellin Laboratories of Chemistry2866
Record Number:CaltechAUTHORS:20151020-073602006
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20151020-073602006
Official Citation:Nuclear Magnetic Resonance Spectroscopy. Long-Range H-F Spin-Spin Coupling in 1,1-Difluoro-2,2-dichloro-3-phenyl-3-methylcyclobutane Masaaki Takahashi, Donald R. Davis, and John D. Roberts Journal of the American Chemical Society 1962 84 (15), 2935-2938 DOI: 10.1021/ja00874a018
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61298
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:20 Oct 2015 18:52
Last Modified:20 Oct 2015 18:52

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