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Long-Range Nuclear Spin-Spin Coupling. Allenic and Polyacetylenic Systems

Snyder, Eugene I. and Roberts, John D. (1962) Long-Range Nuclear Spin-Spin Coupling. Allenic and Polyacetylenic Systems. Journal of the American Chemical Society, 84 (9). pp. 1582-1586. ISSN 0002-7863. doi:10.1021/ja00868a013.

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Spin-spin coupling between protons separated by 5 to 9 chemical bonds has been observed in allenic and polgacetylenic systems. Analysis of the n.m.r. spectrum of 1-chloro-1,2-butadiene by various techniques permits assignment of a sign to J_u opposite to that of J_(12) and J_u. Relation of these results to the theory of proton-proton spin-spin coupling is discussed.

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Additional Information:© 1962 American Chemical Society. Received October 12, 1961. Supported in part by the Office of Naval Research. Postdoctoral Fellow of the Division of Medical Sciences of the United States Public Health Service.
Funding AgencyGrant Number
Office of Naval Research (ONR)UNSPECIFIED
U.S. Public Health Service (USPHS) Postdoctoral FellowUNSPECIFIED
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Caltech Gates and Crellin Laboratories of Chemistry2741
Issue or Number:9
Record Number:CaltechAUTHORS:20151020-073602615
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Official Citation:Long-Range Nuclear Spin-Spin Coupling. Allenic and Polyacetylenic Systems Eugene I. Snyder and John D. Roberts Journal of the American Chemical Society 1962 84 (9), 1582-1586 DOI: 10.1021/ja00868a013
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61300
Deposited By: Ruth Sustaita
Deposited On:20 Oct 2015 19:02
Last Modified:10 Nov 2021 22:47

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