Kaplan, Fred and Roberts, John D. (1961) Nuclear Magnetic Resonance Spectroscopy. Abnormal Splitting of Ethyl Groups due to Molecular Asymmetry. II. Journal of the American Chemical Society, 83 (22). pp. 4666-4668. ISSN 0002-7863. doi:10.1021/ja01483a044. https://resolver.caltech.edu/CaltechAUTHORS:20151020-083705378
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Abstract
Diethyl sulfite,2-5 acetaldehyde diethyl acetal, and cyclopropylcarbinyl ethyl ether offer striking examples of the magnetic non-equivalence of the methylene hydrogens in compounds of the type R-CH_2-O-XR_1R_2R_3 (with R = CH_3 and X = S, C, P, etc.). Thus, the nuclear magnetic resonance (n.m.r.) spectra of such methylene protons are often typical of AB rather than A_2 systems.
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Additional Information: | © 1961 American Chemical Society. Received August 9, 1961. Supported in part by the Office of Naval Research. | |||||||||
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Issue or Number: | 22 | |||||||||
DOI: | 10.1021/ja01483a044 | |||||||||
Record Number: | CaltechAUTHORS:20151020-083705378 | |||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151020-083705378 | |||||||||
Official Citation: | NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY. ABNORMAL SPLITTING OF ETHYL GROUPS DUE TO MOLECULAR ASYMMETRY. II. Fred Kaplan and John D. Roberts Journal of the American Chemical Society 1961 83 (22), 4666-4668 DOI: 10.1021/ja01483a044 | |||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
ID Code: | 61306 | |||||||||
Collection: | CaltechAUTHORS | |||||||||
Deposited By: | Ruth Sustaita | |||||||||
Deposited On: | 20 Oct 2015 18:24 | |||||||||
Last Modified: | 10 Nov 2021 22:47 |
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