CaltechAUTHORS
  A Caltech Library Service

Evidence for Cyclopentyne as a Reaction Intermediate in the Coupling of Phenyllithium with 1-Chlorocyclopentene

Roberts, John D. (1960) Evidence for Cyclopentyne as a Reaction Intermediate in the Coupling of Phenyllithium with 1-Chlorocyclopentene. Journal of the American Chemical Society, 82 (17). pp. 4750-4751. ISSN 0002-7863. http://resolver.caltech.edu/CaltechAUTHORS:20151020-095616175

Full text is not posted in this repository. Consult Related URLs below.

Use this Persistent URL to link to this item: http://resolver.caltech.edu/CaltechAUTHORS:20151020-095616175

Abstract

Evidence has been presented previously for the intervention of benzyne and cyclohexyne as intermediates in nucleophilic substitution reactions of phenyl and cyclohexenyl halides, respectively. In studies designed to determine the minimum ring size for operation of the elimination-addition mechanism, we have now found that an entity with the symmetry properties of cyclopentyne must be involved in the formation of 1-phenylcyclopentene from 1-chlorocyclopentene-1-^(14)C and phenyllithium.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja01502a081DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja01502a081PublisherArticle
Additional Information:© 1960 American Chemical Society. Received July 20, 1960. Supported in part by the Petroleum Research Fund of the American Chemical Society. Grateful acknowledgment is hereby made to the Donors of this Fund.
Funders:
Funding AgencyGrant Number
American Chemical Society Petroleum Research FundUNSPECIFIED
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Caltech Gates and Crellin Laboratories of Chemistry2605
Record Number:CaltechAUTHORS:20151020-095616175
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20151020-095616175
Official Citation:EVIDENCE FOR CYCLOPENTYNE AS A REACTION INTERMEDIATE IN THE COUPLING OF PHENYLLITHIUM WITH 1-CHLOROCYCLOPENTENE John D. Roberts Journal of the American Chemical Society 1960 82 (17), 4750-4751 DOI: 10.1021/ja01502a081
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61317
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:20 Oct 2015 18:12
Last Modified:20 Oct 2015 18:12

Repository Staff Only: item control page